화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.58, 258-265, February, 2018
DOI10.1016/j.jiec.2017.09.035  Export Citation
Influences of solvent media on chain organization and thermochromic behaviors of polydiacetylene assemblies prepared from monomer with symmetric alkyl tails
Chanita Khanantong1, 2, Nipaphat Charoenthai1, 3, †, Sumrit Wacharasindhu4, Mongkol Sukwattanasinitt4, Nisanart Traiphol5, 6, and Rakchart Traiphol2, 7, †
  • 1Department of Chemistry and Research Center for Academic Excellence in Applied Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
  • 2Laboratory of Advanced Polymers and Nanomaterials, Center for Materials Science and Innovation, Faculty of Science, Mahidol University at Salaya, Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170, Thailand
  • 3Research Center for Academic Excellence in Petroleum, Petrochemicals and Advanced Materials, Naresuan University, Phitsanulok 65000, Thailand
  • 4NANOTEC-CU Center of Excellence on Food and Agriculture, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand, Korea
  • 5Laboratory of Advanced Chromic Materials, Department of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand
  • 6Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University, Bangkok 10330, Thailand
  • 7NANOTEC-MU Excellence Center on Intelligent Materials and Systems, Faculty of Science, Mahidol University, Rama 6 Road, Ratchathewi, Bangkok 10400, Thailand
E-mail:,
This contribution investigates thermochromic behaviors and morphologies of polydiacetylene(PDA) assemblies prepared from a diacetylene monomer constituting symmetric alkyl tails. Properties of solvent media strongly affects molecular organization during the preparation process. The use of water provides PDA assemblies with irregular shape while a sheet-like structure forms in butanol. Thermal analysis and X-ray diffraction detect the variation of crystalline fraction and interlamellar spacing in these structures. The change of solvent media significantly affects their thermochromic behaviors. Thin film of PDA assemblies prepared in butanol exhibits reversible thermochromism with much higher color-transition temperature compared to the system of water.
Keywords:Polydiacetylene;Thermochromism;Color transition;Solvent effect;Self-assemblies
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