화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.58, 278-289, February, 2018
DOI10.1016/j.jiec.2017.09.037  Export Citation
Construction of hollow waxberry-like rutile-/anatase-TiO2/SnO2 towards enhanced photocatalysis
Changchao Jia, Hsueh-Shih Chen1, and Ping Yang†
  • School of Material Science and Engineering, University of Jinan, Jinan, 250022, PR China
  • 1Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan
E-mail:
Hollow waxberry-like rutile- and anatase-TiO2/SnO2 (TiO2@SnO2) hierarchical architecture was fabricated for efficient photocatalysis. A Topotactic synthetic method, including the synthesis of CaTiO3/CaSnO3 precursors and subsequent transformation into TiO2@SnO2, was used. Rutile TiO2 nanorods nearly radial alignment grow on the external surface of the hollow sphere composed of anatase TiO2 and SnO2 nanoparticles. Because the hollow hierarchical structure enhances light harvesting ability and the tightly connected interface among different components improves the electron transfer efficiently, a waxberry-like TiO2@SnO2-5% sample with appropriate phase composition exhibits excellent photocatalytic performance. The sample behaved superior cycle stability.
Keywords:Hollow;Waxberry-like;TiO2@SnO2;Hierarchical architecture;Photocatalysis
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