Effects of stabilization variables on mechanical properties of isotropic pitch based carbon fibers

Hyun-Sig Kil; So Young Jang; Seunghyun Ko; Young Pyo Jeon; Hwan-Chul Kim; Han-Ik Joh; Sungho Lee

Journal of Industrial and Engineering Chemistry, Vol.58, 349-356, February, 2018

DOI10.1016/j.jiec.2017.09.048 Export Citation

Effects of stabilization variables on mechanical properties of isotropic pitch based carbon fibers

Hyun-Sig Kil¹, So Young Jang^{1, 2}, Seunghyun Ko^{3, 4}, Young Pyo Jeon^{3, 4}, Hwan-Chul Kim², Han-Ik Joh⁵, and Sungho Lee^{1, 2, †}

¹Carbon Composite Materials Research Center, Korea Institute of Science and Technology, 92 Chudong-ro, Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea
²Department of Organic Materials and Fiber Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, Jeonbuk 54896, Republic of Korea
³Center for C-Industry Incubation, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34114, Republic of Korea
⁴Department of Nano Material Engineering, Korea University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 34113, Republic of Korea
⁵Department of Energy Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Republic of Korea

E-mail:

Optimization of the stabilization process for manufacturing low-cost carbon fibers was performed. By simply varying both heating rate (0.5-10 °C/min) and starting temperature (25-230 °C), the resulting fibers possessed different properties such as densities, oxygen contents, and weight gains due to the oxygen up-takes. Subsequent oxidative reactions led to changes in chemical compositions of the fibers. Therefore, this study suggests that more concerned design with complementary parameters such as starting temperature and heating rate, significantly reducing stabilization time down to 56.5 min with the comparable mechanical properties of the conventional isotropic pitch based CFs.

Keywords:Isotropic pitch;Stabilization;Tensile properties;Carbon fiber

[References]

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Huang X, Materials, 2, 2369 (2009)
Liu Y, Kumar S, Polym. Rev., 52, 234 (2012)
Farsani RE, Fazaeli R, Int. J. Chem. Mol. Nucl. Mater. Metall. Eng., 6, 836 (2012)
Buckley JD, Edie DD, Carbon.Carbon Materials and Composites, William Andrew, New Jersey, 1993.
Yoon SH, Korai Y, Mochida I, Carbon, 32, 281 (1994)
Rahaman MSA, Ismail AF, Mustafa A, Polym. Degrad. Stabil., 92, 1421 (2007)
Matsumoto T, Carbon, 31, 143 (1993)
Didchenko R, Amata CD, US Patent 3954947 (1976).
Fitzer E, Muller DJ, Carbon, 13, 63 (1975)
Tzeng SS, Pan JH, Mater. Chem. Phys., 74(2), 214 (2002)
Hayashi JI, Nakashima M, Kusakabe K, Morooka S, Mitsuda S, Carbon, 33, 1567 (1995)
Fitzer E, Frohs W, Heine M, Carbon, 24, 387 (1986)
Jang SY, Ko S, Jeon YP, Choi J, Kang N, Kim HC, Joh HI, Lee S, J. Ind. Eng. Chem., 45, 316 (2017)
Drbohlav J, Stevenson WTK, Carbon, 33, 693 (1995)
Zhu J, Park SW, Joh HI, Kim HC, Lee S, Macromol. Res., 23(1), 79 (2015)
Ahmad V, Zhongren Y, Youqing F, FTA Report (2012).
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Kissinger HE, J. Res. Natl. Bur. Stand., 57, 217 (1956)
Vyazovkin S, Sbirrazzuoli N, J. Therm. Anal. Calorim., 72, 681 (2003)
Seven KM, Cogen JM, Gilchrist JF, Polym. Eng. Sci., 56(5), 541 (2016)
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Ma J, Meng X, Guo X, Lan Y, Zang S, PLoS One, 12, 1 (2017)
Cho YS, Shim MJ, Kim SW, Mater. Chem. Phys., 52, 94 (1998)
Park JW, Oh SC, Lee HP, Kim HT, Yoo KO, Korean J. Chem. Eng., 17(5), 489 (2000)
Aboulkas A, El Harfi K, El Bouadili A, Energy Conv. Manag., 51(7), 1363 (2010)
Matsumoto T, Mochida I, Carbon, 30, 1041 (1992)
Miura K, Nakagawa H, Hashimoto K, Carbon, 33, 275 (1995)
Robinson KE, Edie DD, Carbon, 34, 13 (1996)
Ogale AA, Lin C, Anderson DP, Kearns KM, Carbon, 40, 1309 (2002)
Vilaplana-Ortego E, Alcaniz-Monge J, Cazorla-Amoros D, Linares-Solano A, Carbon, 41, 1001 (2003)
Wazir AH, Kakakhel L, New Carbon Mater, 24, 83 (2009)
Kim BJ, Kil H, Watanabe N, Seo MH, Kim BH, Yang KS, Kato O, Miyawaki J, Mochida I, Yoon SH, Curr. Org. Chem., 17, 1463 (2013)
Kim BJ, Eom Y, Kato O, Miyawaki J, Kim BC, Mochida I, Yoon SH, Carbon, 77, 747 (2014)
Park MS, Ko Y, Jung MJ, Lee YS, Carbon Lett, 16, 121 (2015)
Yang J, Nakabayashi K, Miyawaki J, Yoon SH, Carbon, 106, 28 (2016)
Kim J, Im US, Lee B, Peck DH, Yoon SH, Jung DH, Carbon Lett., 19, 72 (2016)
Yuan G, Li X, Xiong X, Dong Z, Westwood A, Li B, Ye C, Ma G, Cui Z, Cong Y, Zhang J, Li Y, Carbon, 115, 59 (2017)
Desimoni E, Casella GI, Morone A, Salvi AM, Surf. Interface Anal., 15, 627 (1990)
Shono H, Matsumoto M, Wang X, Takeuchi M, Sendoda Y, Ishihara A, Kabe T, Sekiyu Gakkaishi, 34, 510 (1991)
Boudou JP, Paredes JI, Cuesta A, Martinez-Alonso A, Tascon JMD, Carbon, 41, 41 (2003)
Moreno-Castilla C, Lopez-Ramon MV, Carrasco-Marin F, Carbon, 38, 1995 (2000)
Lim TH, Yeo SY, Sci. Rep., 7, 4733 (2017)

[Referenced By]

[1] Ruland W, Carbon Fibers Adv. Mater., 2, 528 (1990)

[2] Huang X, Materials, 2, 2369 (2009)

[3] Liu Y, Kumar S, Polym. Rev., 52, 234 (2012)

[4] Farsani RE, Fazaeli R, Int. J. Chem. Mol. Nucl. Mater. Metall. Eng., 6, 836 (2012)

[5] Buckley JD, Edie DD, Carbon.Carbon Materials and Composites, William Andrew, New Jersey, 1993.

[6] Yoon SH, Korai Y, Mochida I, Carbon, 32, 281 (1994)

[7] Rahaman MSA, Ismail AF, Mustafa A, Polym. Degrad. Stabil., 92, 1421 (2007)

[8] Matsumoto T, Carbon, 31, 143 (1993)

[9] Didchenko R, Amata CD, US Patent 3954947 (1976).

[10] Fitzer E, Muller DJ, Carbon, 13, 63 (1975)

[11] Tzeng SS, Pan JH, Mater. Chem. Phys., 74(2), 214 (2002)

[12] Hayashi JI, Nakashima M, Kusakabe K, Morooka S, Mitsuda S, Carbon, 33, 1567 (1995)

[13] Fitzer E, Frohs W, Heine M, Carbon, 24, 387 (1986)

[14] Jang SY, Ko S, Jeon YP, Choi J, Kang N, Kim HC, Joh HI, Lee S, J. Ind. Eng. Chem., 45, 316 (2017)

[15] Drbohlav J, Stevenson WTK, Carbon, 33, 693 (1995)

[16] Zhu J, Park SW, Joh HI, Kim HC, Lee S, Macromol. Res., 23(1), 79 (2015)

[17] Ahmad V, Zhongren Y, Youqing F, FTA Report (2012).

[18] Morgan P, Carbon Fibers and Their Composites, CRC Press, Taylor & Francis Group, Florida, 2005.

[19] Kissinger HE, J. Res. Natl. Bur. Stand., 57, 217 (1956)

[20] Vyazovkin S, Sbirrazzuoli N, J. Therm. Anal. Calorim., 72, 681 (2003)

[21] Seven KM, Cogen JM, Gilchrist JF, Polym. Eng. Sci., 56(5), 541 (2016)

[22] Rantuch P, Kacikova D, Nagypal B, Eur. J. Environ. Saf. Sci., 2, 12 (2014)

[23] Ma J, Meng X, Guo X, Lan Y, Zang S, PLoS One, 12, 1 (2017)

[24] Cho YS, Shim MJ, Kim SW, Mater. Chem. Phys., 52, 94 (1998)

[25] Park JW, Oh SC, Lee HP, Kim HT, Yoo KO, Korean J. Chem. Eng., 17(5), 489 (2000)

[26] Aboulkas A, El Harfi K, El Bouadili A, Energy Conv. Manag., 51(7), 1363 (2010)

[27] Matsumoto T, Mochida I, Carbon, 30, 1041 (1992)

[28] Miura K, Nakagawa H, Hashimoto K, Carbon, 33, 275 (1995)

[29] Robinson KE, Edie DD, Carbon, 34, 13 (1996)

[30] Ogale AA, Lin C, Anderson DP, Kearns KM, Carbon, 40, 1309 (2002)

[31] Vilaplana-Ortego E, Alcaniz-Monge J, Cazorla-Amoros D, Linares-Solano A, Carbon, 41, 1001 (2003)

[32] Wazir AH, Kakakhel L, New Carbon Mater, 24, 83 (2009)

[33] Kim BJ, Kil H, Watanabe N, Seo MH, Kim BH, Yang KS, Kato O, Miyawaki J, Mochida I, Yoon SH, Curr. Org. Chem., 17, 1463 (2013)

[34] Kim BJ, Eom Y, Kato O, Miyawaki J, Kim BC, Mochida I, Yoon SH, Carbon, 77, 747 (2014)

[35] Park MS, Ko Y, Jung MJ, Lee YS, Carbon Lett, 16, 121 (2015)

[36] Yang J, Nakabayashi K, Miyawaki J, Yoon SH, Carbon, 106, 28 (2016)

[37] Kim J, Im US, Lee B, Peck DH, Yoon SH, Jung DH, Carbon Lett., 19, 72 (2016)

[38] Yuan G, Li X, Xiong X, Dong Z, Westwood A, Li B, Ye C, Ma G, Cui Z, Cong Y, Zhang J, Li Y, Carbon, 115, 59 (2017)

[39] Desimoni E, Casella GI, Morone A, Salvi AM, Surf. Interface Anal., 15, 627 (1990)

[40] Shono H, Matsumoto M, Wang X, Takeuchi M, Sendoda Y, Ishihara A, Kabe T, Sekiyu Gakkaishi, 34, 510 (1991)

[41] Boudou JP, Paredes JI, Cuesta A, Martinez-Alonso A, Tascon JMD, Carbon, 41, 41 (2003)

[42] Moreno-Castilla C, Lopez-Ramon MV, Carrasco-Marin F, Carbon, 38, 1995 (2000)

[43] Lim TH, Yeo SY, Sci. Rep., 7, 4733 (2017)