화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.2, 479-488, February, 2018
DOI10.1007/s11814-017-0311-y  Export Citation
Adsorptive performance of calcined Cardita bicolor for attenuating Hg(II) and As(III) from synthetic and real wastewaters
Abolfazl Teimouri, Hossein Esmaeili1, Rauf Foroutan1, and Bahman Ramavandi2, †
  • Department of Chemical Engineering, School of Chemical Engineering, Kherad Institute of Higher Education, Bushehr, Iran
  • 1Department of Chemical Engineering, Bushehr Branch, Islamic Azad University, Bushehr, Iran
  • 2Department of Environmental Health Engineering, Bushehr University of Medical Sciences, 7518759577 Bushehr, Iran
E-mail:
The first application of calcined Cardita bicolor oyster shell (CCBS) for Hg(II) and As(III) adsorption from synthetic and real wastewaters was tested. The main elements in CCBS structure were carbon, oxygen, magnesium, phosphor, and calcium. Effects of different parameters like initial pH, contact time, temperature, and CCBS dosage were assessed. The results showed that the maximum recovery of Hg(II) and As(III) adsorption was determined as C0=10mg/L, t=80 min, T=25 °C, CCBS dosage=5 g/L, and pH=6 (for mercury ion) and 7 (for arsenic ion). In these conditions, 95.72% Hg(II) and 96.88% As(III) were removed from aqueous solution. The correlation coefficient (R2) values for both adsorbates were obtained >0.98 and >0.96 for Langmuir and Freundlich isotherm models, respectively. Pseudo-second-order kinetic model was more capable to describe kinetic behavior of adsorption process of both metal ions in comparison with pseudo-first-order model. The half life (t1/2) value for Hg(II) and As(III) with initial concentration of 10mg/L was 4.032 and 4.957 min, respectively. Moreover, thermodynamic parameters of enthalpy (ΔHo), entropy (ΔSo), and Gibbs free energy (ΔGo) were investigated. Two real wastewaters obtained from a leather factory and a landfill leachate were successfully treated using CCBS. The results confirmed that adsorption process of metals ions was exothermic and spontaneous.
Keywords:Cardita bicolor;Adsorption Isotherm;Hg(II);As(III);Kinetic Behavior;Real Wastewater
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