화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Materials Research, Vol.28, No.1, 50-61, January, 2018
DOI10.3740/MRSK.2018.28.1.50  Export Citation
EDLC 전극용 카본에어로젤의 합성조건에 따른 기공구조 및 전기화학적 특성
Pore Structure and Electrochemical Properties of Carbon Aerogels as an EDLC-Electrode with Different Preparation Conditions
서혜인, 정지철, 김명수†
  • 명지대학교 화학공학과
Seo Hye Inn, Ji Chul Jung, and Myung-Soo Kim†
  • Department of Chemical Engineering, Myongji University, Yongin, Gyeonggi-do 17058, Republic of Korea
E-mail:
Various carbon aerogels (CAs) were prepared from polymerization of resorcinol and formaldehyde and applied as the electrode materials of an electric double layer capacitor (EDLC) with the aim of controlling the textural and electrochemical properties of CAs by the type of base catalyst and the ratio of resorcinol to catalyst (R/C). The CAs from NaHCO3 and KHCO3 with H+ ions had higher specific surface areas but exhibited lower electrochemical properties than those from K2CO3 and Na2CO3, which had more uniform pore size distributions. The electrochemical properties of Na2CO3 were superior to those of K2CO3 probably because the polarizing power of Na+ ions was higher than K+ ions. With an increasing R/C ratio, the pore sizes of CA showed a tendency to increase but the uniformity of the pore size distribution got worse. For the four base catalysts, the highest electrochemical property was obtained at the R/C ratio of 500.
Keywords:carbon aerogel;catalyst;pore size distribution;EDLC;electrochemical property
  1. Zhang LL, Zhao XS, Chem. Soc. Rev., 38, 2520 (2009)
  2. Qu DY, Shi H, J. Power Sources, 74(1), 99 (1998)
  3. Zhai YP, Dou YQ, Zhao DY, Fulvio PF, Mayes RT, Dai S, Adv. Mater., 23(42), 4828 (2011)
  4. Noked M, Soffer A, Aurbach D, J. Solid State Electr., 15, 1563 (2011)
  5. Frackowiak E, Phys. Chem. Chem. Phys., 9, 1774 (2007)
  6. Frackowiak E, Abbas Q, Beguin F, J. Energy Chem., 22, 227 (2013)
  7. Lee HM, Kim HG, An KH, Kim BJ, J. Nanosci. Nanotechnol., 15, 8797 (2015)
  8. Rufford TE, Jurcakova DH, Fiset E, Zhu Z, Lu GQ, Electrochem. Commun., 11, 974 (2009)
  9. Lee HM, Kim HG, An KH, Kim BJ, Carbon Lett., 15, 71 (2014)
  10. Fu YP, Cai X, Wu HW, Lv ZB, Hou SC, Peng M, Yu X, Zou DC, Adv. Mater., 24(42), 5713 (2012)
  11. Lee EJ, Lee YJ, Kim JK, Lee M, Yi J, Yoon JR, Song JC, Song IK, Mater. Res. Bull., 70, 209 (2015)
  12. Tamon H, Ishizaka H, Araki T, Okazaki M, Carbon, 36, 1257 (1998)
  13. Job N, Pirard R, Marien J, Pirard JP, Carbon, 42, 619 (2004)
  14. Wu ZS, Zhou G, Yin LC, Ren W, Li F, Cheng HM, Nano. Energy, 1, 107 (2012)
  15. Vivekchand SRC, Rout CS, Subrahmanyam KS, Govindaraj A, Rao CNR, J. Chem. Sci., 120, 9 (2008)
  16. Fan ZJ, Yan J, Wei T, Zhi LJ, Ning GQ, Li TY, Wei F, Adv. Funct. Mater., 21(12), 2366 (2011)
  17. Chmiola J, Yushin G, Dash R, Gogotsi Y, J. Power Sources, 158(1), 765 (2006)
  18. Biener J, Stadermann M, Suss M, Worsley MA, Biener MM, Rose KA, Baumann TF, Energy Environ. Sci., 4, 656 (2011)
  19. Zuo L, Zhang Y, Zhang L, Miao YE, Fan W, Liu T, Materials, 5, 6806 (2015)
  20. Pierre AC, Pajonk GM, Chem. Rev., 102(11), 4243 (2002)
  21. Pekala RW, J. Mater. Sci., 24, 3221 (1989)
  22. Liu N, Shen J, Liu D, Microporous Mesoporous Mater., 167, 23 (2013)
  23. Al-Muhtaseb SA, Ritter JA, Adv. Mater., 15(2), 101 (2003)
  24. ElKhatat AM, Al-Muhtaseb SA, Adv. Mater., 23(26), 2887 (2011)
  25. Taylor SJ, Haw MD, Sefcik J, Fletcher AJ, Langmuir, 30(34), 10231 (2014)
  26. Yamamoto T, Yoshida T, Suzuki T, Mukai SR, Tamon H, J. Colloid Interface Sci., 245(2), 391 (2002)
  27. Yang I, Kim SG, Kwon SH, Kim MS, Jung JC, Electrochim. Acta, 223, 21 (2017)
  28. Tsuchiya T, Mori T, Iwamura S, Ogino I, Mukai SR, Carbon, 76, 240 (2014)
  29. Brandt R, Petricevic R, Probstle H, Fricke J, J. Porous Mat., 10, 171 (2003)
  30. Hamano Y, Tsujimura S, Shirai O, Kano K, Mater. Lett., 128, 191 (2014)
  31. Lin C, Ritter JA, Carbon, 35, 1271 (1997)
  32. Hwang SW, Hyun SH, J. Non-Cryst. Solids, 347, 238 (2004)
  33. Horikawa T, Hayashi J, Muroyama K, Carbon, 42, 1625 (2004)
  34. Wang W, Liu P, Zhang M, Hu J, Xing F, J. Compos. Mater., 2, 104 (2012)
  35. Mezzavilla S, Zanella C, Aravind PR, Della Volpe C, Soraru GD, J. Mater. Sci., 47(20), 7175 (2012)
  36. Feng J, Feng J, Zhang C, J. Sol-Gel Sci. Technol., 59, 371 (2011)
  37. Job N, Thery A, Pirard R, Mariea J, Kocon L, Beguin JRR, Pirard J, Carbon, 43, 2481 (2005)
  38. Lee YJ, Jung JC, Yi J, Baeck SH, Yoon JR, Song IK, Curr. Appl. Phys., 10(2), 682 (2010)
  39. Kotz R, Carlen M, Electrochim. Acta, 45(15-16), 2483 (2000)
  40. Kwon SH, Lee EJ, Kim BS, Kim SG, Lee BJ, Kim MS, Jung JC, Korean J. Chem. Eng., 14, 603 (2014)
  41. Chmila J, Yushin G, Gogotsi Y, Portet C. Simon P, Taberna PL, Science, 313, 1760 (2006)
  42. Largeot C, Portet C. Chmiola J, Taberna PL, Gogotsi Y, Simon P, J. Am. Chem. Soc., 130, 2790 (2008)
  43. Chmiola J, Largeot C, Taberna PL, Simon P, Gogotsi Y, Angew. Chem.-Int. Edit., 120, 3440 (2008)
  44. Fairen-Jimenez D, Carrasco-Marin F, Moreno-Castilla C, Carbon, 44, 2301 (2006)
  45. Chen JS, Diard JP, Durand R, Montella C, J. Electroanal. Chem., 406(1-2), 1 (1996)
  46. Jang JH, Oh SM, J. Korean Electrochem. Soc., 13, 223 (2010)
  47. Kunz W, Henle J, Ninham BW, Curr. Opin. Colloid Interface Sci., 9, 19 (2004)