Polyaniline (PANI)/TiO2 composite graphene hydrogel was successfully prepared by chemical reduction method. TiO2 and PANI were uniformly dispersed in the three-dimensional network of graphene hydro gels. This rich network of macroscopic structures not only provides desirable conditions for synergistic adsorption and photocatalytic degradation of pollutants, but also improves the chemical stability of composites. Specifically, 80% PANI/TiO2-reduced graphene oxide hydrogel (rGH) can completely degrade BPA in 40 min, and BPA was almost completely mineralized into small molecules in 65 min. After five cycles of experiments, the degradation rate of PANI/TiO2-rGH for BPA was more than 90%. XPS analysis indicated that there is a strong interaction between PANI and TiO2. Hydrogen bonding between TiO2 and rGH was also demonstrated. Quenching experiments indicated center dot O-2(-) and h(+) are the main active species in the degradation of BPA by PANI/TiO2-rGH and center dot OH and h(+) are the main active species by PANI/TiO2, suggesting that rGH and PANI acts as a transmitter for e-and h(+), respectively. (C) 2017 Published by Elsevier B.V.