Chemical looping air separation (CLAS) provides a novel route for O-2 production, which can be coupled with integrated gasification combined cycle (IGCC) or oxy-fuel combustion to address the O-2 source issue. The development of regenerable and robust oxygen carrier, which should be able to release gaseous oxygen in O-2 deficient atmosphere (usually CO2/H2O) and regenerate itself by oxidizing with O-2 in air, is critical for the successful deployment of CLAS systems. In this work, a CuO@TiO2-Al2O3 oxygen carrier with hierarchical structure (i.e., CuO-rich, TiO2-stabilized and Al2O3-supported), which was prepared by the self-assembly template combustion synthesis (SATCS) method, was adopted for continuous oxygen production in a paralleled fluidized bed reactor. Before which, isothermal experiments in a thermogravimetric analyzer (TGA) were first conducted to analyze the effect of temperature on OC decoupling and regeneration characteristics. The influence of inlet gas flow rate on the oxygen decoupling rate of the oxygen carrier was then investigated in a batch fluidized bed reactor. Appropriate reaction temperature as well as inlet gas flow rate for continuous O-2 production in the paralleled fluidized bed reactor was ultimately attained. During a consecutive operation of 10 h, continuous stream of O-2/CO2 with relatively stable and high O-2 concentration (19.7-27.6 vol, steam free basis) was obtained. The superior reactivity and stability of CuO@TiO2-Al2O3 achieved during the continuous operation in the paralleled fluidized bed reactor indicate that it could be a promising oxygen carrier candidate for the CLAS process.