화학공학소재연구정보센터
Chemical Engineering Journal, Vol.332, 370-376, 2018
3D spongy CoS2 nanoparticles/carbon composite as high-performance anode material for lithium/sodium ion batteries
A spongy CoS2/carbon composite assembled from CoS2 nanoparticles (similar to 20 nm) homogeneously anchored on a spongy carbon matrix was synthesized through a facile freeze-drying method and a hydrothermal process. As anode material for lithium/sodium ion batteries (LIBs/SIBs), this composite shows significantly enhanced lithium/sodium storage performance with the synergetic effects due to the electrical conductivity of the carbon matrix and the porous structure, which provide buffer spaces for volume expansion during charge/discharge processes and feasible transfer pathways for electrons/ions. The electrochemical results demonstrate that the spongy CoS2/carbon composite is an outstanding anode material for LIBs and SIBs. It delivers a high specific capacity of 610 mAh g(-1) at 500 mA g(-1) after 120 cycles in LIBs and 330 mAh g(-1) at 500 mA g(-1) after 60 cycles in SIBs, respectively. Moreover, the freeze-drying/hydrothermal process developed in this work could be useful for the construction of many other high-capacity metal sulfide composites as electrode materials for sodium ion batteries.