Herein, with the aim of shedding light on the effect of non-ionic co-solute (carbohydrate) stereochemistry on the aggregation and surface behaviour of ionic liquid-based surfactant 1-decyl-3methylimidazolium bromide ([C(10)mim][Br]) in aqueous solution, we studied the surface tension, electrical conductivity, volumetric and compressibility properties for the aqueous solutions of [C(10)mim][Br] in the presence of different sugars containing pentose monosaccharides (xylose, ribose and arabinose), hexose monosaccharides (glucose, and mannose), disaccharides (sucrose and lactose) and trisaccharide (raffinose) at different temperatures. From the electrical conductivity measurements, the values of the degree of ionization of the counter ion on the micelles (alpha) and thermodynamic properties of micellization (DGm) for [C(10)mim][Br] in aqueous carbohydrate solutions were obtained. The various parameters such as apparent molar volume (V-phi), isentropic compressibility (js), apparent molar isentropic compressibility (K-phi) and the change of apparent molar properties upon micellization (Delta V-phi m and Delta K-phi m) were derived from the experimental density and speed of sound data. The surface tension measurements provided a series of parameters, including surface tension at the cmc (Pi(cmc)), effectiveness of surface tension reduction (Pi(cmc)), maximum surface excess concentration (Gamma(max)) and minimum surface area per molecule (A(min)) at interface of air/solution for the investigated surfactant in the presence of different sugars at 298.15 K. All the investigated carbohydrates have soluting-out effect (favouring the micelle formation) and their abilities to reduce the cmc of [C(10)mim][Br] in aqueous solutions increase with an increase in the hydrophilicity of the carbohydrate. (C) 2017 Published by Elsevier Ltd.