Journal of Crystal Growth, Vol.483, 251-257, 2018
Investigating new activators for small-bandgap LaX3 (X = Br, I) scintillators
Luminescence and scintillation properties of Bi3+, Sb3+, and Eu2+-doped LaI3 and LaBr3 were explored. Out of the three dopants investigated, Eu2+ was the most promising new activator for small-bandgap LaX3 (X = Br, I) and was further studied in the mixed-halide LaBr3-xIx. Crystals were grown from the melt using the vertical Bridgman method. LaBr3:Eu2+ 0.5% ( mol) had the most favorable scintillation properties with a light output of 43,000 ph/MeV and 6% energy resolution at 662 keV. Performance of LaBr3-xIx:Eu2+ worsened for most samples as iodide concentration was increased. Room-temperature scintillation of LaI3:Eu2+ 0.1% and 0.5% was observed and is the first case of room-temperature emission reported for doped LaI3. (C) 2017 Elsevier B.V. All rights reserved.
Keywords:Characterization;Bridgman technique;Growth from melt;Halides;Rare earth compounds;Scintillators