화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.101, No.32, 6123-6126, 1997
Evidence for Molecular Translational Diffusion During the Crystallization of Amorphous Solid Water
Molecular diffusion in amorphous solid water is studied by measuring the extent of isotope exchange and mixing in vapor-deposited ultrathin films using temperature-programmed desorption. Our results indicate there is long-range translational diffusion that occurs concomitantly with the amorphous to crystalline ice phase transition. The apparent diffusivity estimated from these data is a factor of 10(6+/-1) greater than an Arrhenius extrapolation for diffusion in crystalline ice. This finding suggests that the amorphous material exhibits liquid-like translational diffusion prior to crystallization at temperatures near 155 K.