The nature of the Ni(II) phase formed on silica during the preparation by deposition-precipitation (DP) of Ni/SiO2 samples is shown to depend on the silica surface area and the time of deposition -precipitation. Ni/SiO2 samples have been characterized by XRD, IR, EXAFS, TPR, TEM, STEM-EDX, and BET. With silica of low surface area and for short DP time (less than or equal to 4 h), the Ni(II)) phase is mainly a turbostratic nickel hydroxide with a small amount of 1:1 nickel phyllosilicate. However, silica of high surface area and for short DP lime (less than or equal to 100 min), the Ni(II) phase is mainly a I:1 nickel phyllosilicate. For longer DP time (>4 h) and with both types of silica, the Ni(II) phase is an ill-crystallized 1:I nickel phyllosilicate. However, the latter is better crystallized with silica of low surface area. Almost the same Ni(II) phases were obtained whether silica was porous or not. However, the Ni(II) phase is better crystallized and the interface with the support is larger with nonporous silica than with porous one.