Functional carbon materials have recently attracted attention as positive electrode active materials for Al rechargeable batteries in conjunction with an Al negative electrode and a chloroaluminate ionic liquid electrolyte. This study explores a new carbon material, a graphene-decorated activated carbon fiber cloth (ACFC), for the positive electrode. Graphene-decorated ACFCs can be used in a binder-free manner and will directly contribute to increased gravimetric capacity of the whole electrode [mAh (g(electrode))(-1), not per the active material]. Specifically, the positive electrode behaviors of three types of ACFC-based electrodes are examined in a Lewis acidic AlCl3-1-ethyl-3-methylimidazolioum chloride ([C(2)mim] Cl) room-temperature ionic liquid. Uncoated and low-loading graphene-coated ACFC electrodes show an electric double layer capacitor (EDLC)-like behavior, whereas the intercalation/deintercalation reaction of chloroaluminate anion (e.g., [AlCl4](-)) is observed for the high-loading graphene-coated one. These electrodes exhibit a good cyclability and satisfactory coulombic efficiency up to 800 cycles at a current density of 500 mA g(-1). (C) The Author(s) 2017. Published by ECS. All rights reserved.