Journal of Physical Chemistry B, Vol.102, No.7, 1212-1218, 1998
Energy of interaction between solid surfaces and liquids
We consider the wetting transition on a planar surface in contact with a semi-infinite fluid. In the classical approach, the surface is assumed to be solid, and when interaction between solid and fluid is sufficiently short-range, the contribution of the fluid can be represented by a. surface free energy with a density of the form Phi(rho(s)), where rho(s) is the limiting density of the fluid at the surface. In the present paper we propose a more precise representation of-the surface energy that takes into account not only the value of rho(s) but also the contribution from the whole density profile rho(z) of the fluid, where z is the coordinate normal to the surface, The specific value of the functional of rho(s) at the surface is expressed in mean-field approximation through the potentials of intermolecular interaction and some other parameters of the fluid and the solid wall. An extension to the case of fluid mixtures in contact with a solid surface is proposed.