Transparent dye-sensitized solar cells (DSSCs) can be coupled within a building's architecture to provide day lighting and electrical power simultaneously. In this work, the relationship between the transparency and performance of DSSCs is studied by changing the TiO2 electrode thickness. The 10 pm thickness device shows a power conversion efficiency of 5.93% and a J(sc) of 12.75 mA/cm(2) with 37% transparency in the visible range. However, the performance loss in DSSCs during the scale up process is a potential drawback. This can be addressed using an optical concentrator with DSSC to generate more power from small size devices. Here, a compound parabolic concentrator (CPC) is coupled with DSSCs and its performance is compared to a scaled-up device (approx. 4 times). Furthermore, the impact of operating temperature on the performance of the bare and concentrator-coupled devices is discussed in this article. An increase of 67% in power conversion efficiency is observed at 36 degrees C for the concentrator-coupled device under 1000 W/m(2) illumination. Maximum Jsc of 25.55 mA/cm(2) is achieved at 40 degrees C for the concentrated coupled device compare with the J(sc) of 13.06 mA/cm(2) for the bare cell at the same temperature.