화학공학소재연구정보센터
Thermochimica Acta, Vol.658, 63-67, 2017
Enthalpy of formation and lattice energy of bismuth perrhenate doped by neodymium and indium oxides
For the first time the standard formation enthalpy of Bi2.5Nd1.4In0.1ReO24.5 has been determined by solution calorimetry by combining the solution enthalpies of Bi2.5Nd1.4In0.1ReO24.5, 1.4NdCl(3) + 0.1InCl(3)0.1InCl(3) mixture in 2 M HCl and literature data. The lattice energy for Bi2.5Nd1.4In0.1ReO24.5 has been calculated using Born Haber cycle. The dependence of lattice energy for Bi2.5Nd1.4In0.1ReO24.5 (R - rare earth element) from radius of rare earth metal was constructed. It was established that dependence was linear and had form: U-lat = -129450 + 45070 r(R). Linear character of experimentally obtained dependence was explained using modified variant of Kapustinskii formula obtained by us as following: U = A + Br-R.