화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 56-63, March, 2018
DOI10.1016/j.jiec.2017.10.005  Export Citation
Characteristics of a novel adsorbent Fe.Mg-type hydrotalcite and its adsorption capability of As(III) and Cr(VI) from aqueous solution
Fumihiko Ogata1, Erimi Ueta1, and Naohito Kawasaki1, 2, †
  • 1Faculty of Pharmacy, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
  • 2Antiaging Center, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail:
In the present study, we prepared a newly adsorbent, Iron.Magnesium-type hydrotalcite (FHT), at different molar ratios (FHT3.0; Mg2+/Fe3+ = 3.0 and FHT5.0; Mg2+/Fe3+ = 5.0) for removing heavy metal ions. Characteristics of FHT and arsenite (As(III)) and hexavalent chromium (Cr(VI)) adsorption capability onto that were evaluated. Amount adsorbed of As(III) and Cr(VI) increased with raising temperatures. Amount adsorbed of heavy metal ions onto FHT in the single liquid phase was smaller than that in the mixed liquid phase, which suggests that the amount adsorbed was affected by the adsorbent properties, interlayer space, and solution pH.
Keywords:Iron.magnesium-type hydrotalcite;As(III);Cr(VI);Adsorption
  1. Mohan D, Pittman CU, J. Hazard. Mater., 142(1-2), 1 (2007)
  2. Sanchez-Cantu M, Galicia-Aguilar JA, Santamaria-Juarez D, Hernandez-Moreno LE, Appl. Clay Sci., 121-122, 146 (2016)
  3. Kumara ASK, Jiang SJ, J. Environ. Chem. Eng., 4, 1698 (2016)
  4. Luo XB, Wang CC, Luo SL, Dong RZ, Tu XM, Zeng GS, Chem. Eng. J., 187, 45 (2012)
  5. Boddu VM, Abburi K, Talbott JL, Smith ED, Haasch R, Water Res., 42, 633 (2008)
  6. Deng L, Shi Z, Li B, Yang L, Luo L, Yang X, J. Eng. Chem. Res., 53, 7746 (2014)
  7. Xu YF, Zhang J, Qian GR, Ren Z, Xu ZP, Wu YY, Liu Q, Qiao SZ, Ind. Eng. Chem. Res., 49(6), 2752 (2010)
  8. Hu J, Lo IMC, Chen GH, Langmuir, 21(24), 11173 (2005)
  9. Turk T, Alp I, J. Ind. Eng. Chem., 20(2), 732 (2014)
  10. Perez E, Ayele L, Getachew G, Fetter G, Bosch P, Mayoral A, Diaz I, J. Environ. Chem. Eng., 3, 1555 (2015)
  11. Qiu W, Zheng Y, J. Hazard. Mater., 148(3), 721 (2007)
  12. Aliane A, Bounatiro N, Cherif AT, Akretche DE, Water Res., 35, 2320 (2001)
  13. Gheju M, Balcu I, J. Hazard. Mater., 196, 131 (2011)
  14. Rengaraj S, Yeon KH, Moon SH, J. Hazard. Mater., 87(1-3), 273 (2001)
  15. Maleki A, Hayati B, Naghizadeh M, Joo SW, J. Ind. Eng. Chem., 28, 211 (2015)
  16. Sigdel A, Park J, Kwak H, Park PK, J. Ind. Eng. Chem., 35, 277 (2016)
  17. Mishra S, Verma N, J. Ind. Eng. Chem., 36, 346 (2016)
  18. Gottipati R, Mishra S, J. Ind. Eng. Chem., 36, 355 (2016)
  19. Wang S, Gao B, Li Y, J. Ind. Eng. Chem., 37, 361 (2016)
  20. Zhenzhong L, Huiping D, Jian Z, Res. Environ, 5, 23 (2007)
  21. Xiao LL, Ma W, Han M, Cheng ZH, J. Hazard. Mater., 186(1), 690 (2011)
  22. Cavani F, Trifiro F, Vaccari A, Catal. Today, 11, 173 (1991)
  23. Reichle WT, J. Catal., 94, 547 (1985)
  24. Mandal S, Mayadevi S, Appl. Clay Sci., 40, 54 (2008)
  25. Jobbagy M, Regazzoni AE, J. Colloid Interface Sci., 393, 314 (2013)
  26. Miyata S, Clay Clay Min., 31, 305 (1983)
  27. Israeli Y, Taviot-Gueho C, Besse JP, Morel JP, Morel-Desrosiers N, J. Chem. Soc.-Dalton Trans., 5, 791 (2000)
  28. Morel-Desrosiers N, Pisson J, Israeli T, Taviot-Gueho C, Besse JP, Morel JP, J. Mater. Chem., 13, 2582 (2003)
  29. Turk T, Alp I, Deveci H, J. Hazard. Mater., 171(1-3), 665 (2009)
  30. Grover K, Komarneni S, Katsuki H, Water Res., 43, 3884 (2009)
  31. Paikaray S, Hendry MJ, Appl. Clay Sci., 77-78, 33 (2013)
  32. Liu R, Frost RL, Martens WN, Water Res., 43, 1323 (2009)
  33. Ferreira OP, de Moraes SG, Duran N, Cornejo L, Alves OL, Chemosphere, 62, 80 (2006)
  34. Hirahara H, Sawai Y, Aisawa S, Clay Sci. Soc. Japan, 43, 70 (2002)
  35. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  36. Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
  37. Das J, Patra BS, Baliarsingh N, Parida KM, J. Colloid Interface Sci., 316(2), 216 (2007)
  38. Abe I, Hayashi K, Kitagawa M, J. Jpn. Oil Chem., 25, 145 (1976)
  39. Liu X, Zhang LF, Powder Technol., 277, 112 (2015)
  40. Saleh TA, Sarı A, Tuzen M, J. Mol. Liq., 219, 937 (2016)
  41. Ogata F, Imai D, Kawasaki N, J. Environ. Chem. Eng., 3, 1476 (2015)
  42. Gu B, Schmitt J, Chen Z, Liang L, McCarthy JF, Environ. Sci. Technol., 28, 38 (1994)
  43. Li Q, Yue QY, Su Y, Gao BY, Sun HJ, Chem. Eng. J., 158(3), 489 (2010)
  44. Ren H, Jiang J, Wu D, Gao Z, Sun Y, Luo C, Water Air Soil Pollut., 227, 101 (2016)
  45. Chetia M, Goswamee RL, Banerjee S, Chatterjee S, Singh L, Srivastava RB, Sarma HP, Clean Technol. Environ. Policy, 14, 21 (2012).
  46. Cullen WR, Reimer KJ, Chem. Rev., 89, 713 (1989)
  47. Smedley PL, Kinniburgh DG, Appl. Geochem., 17, 517 (2002)
  48. Jain A, Raven KP, Loeppert RH, Environ. Sci. Technol., 33, 1179 (1999)
  49. Raven KP, Jain A, Loeppert RH, Environ. Sci. Technol., 32, 344 (1998)
  50. Wu N, Wei HH, Zhang LZ, Environ. Sci. Technol., 46, 419 (2012)
  51. Cotton FA, Wilkinson G, Advanced Inorganic Chemistry, 5th ed., Wiley, New York, 1999.
  52. Gheju M, Balcu I, Mosoarca G, J. Hazard. Mater., 310, 270 (2016)
  53. Ogata F, Kawasaki N, Chem. Pharm. Bull., 62, 1014 (2015)
  54. Ookubo A, Ooi K, Tani F, Hayashi H, Langmuir, 10(2), 407 (1994)
  55. Jobbagy M, Regazzoni AE, J. Colloid Interface Sci., 393, 314 (2013)
  56. Hattori T, Takahashi H, Matsuda M, Miyake M, J. Soc. Inorg. Mater. Japan, 11, 113 (2004)
  57. Javier G, Maria M, de Joan P, Miquel R, Lara D, J. Hazard. Mater., 147, 575 (2007)
  58. Matsunaga H, Yokoyama T, Eldridge RJ, Bolto BA, React. Funct. Polym., 29(3), 167 (1996)
  59. Chetia M, Goswamee RL, Banerjee S, Chatterjee S, Singh L, Srivastava RB, Sarma HP, Clean Technol. Environ. Policy, 14, 21 (2012).
  60. Selvi K, Pattabhi S, Kadirvelu K, Bioresour. Technol., 80(1), 87 (2001)
  61. Dubey SP, Gopal K, J. Hazard. Mater., 145(3), 465 (2007)