화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 160-168, March, 2018
DOI10.1016/j.jiec.2017.10.020  Export Citation
A supercritical ethanol route for one-pot synthesis of tin sulfide-reduced graphene oxides and their anode performance for lithium ion
Mugyeom Choi1, Wendy William2, Jieun Hwang1, Dohyeon Yoon1, and Jaehoon Kim1, 2, †
  • 1School of Mechanical Engineering, Sungkyunkwan University, 2066 Seobu-Ro, Jangan-Gu, Suwon, Gyeong Gi-Do, 16419, Republic of Korea
  • 2SKKU Advanced Institute of Nano Technology (SAINT), Sungkyunkwan University, 2066 Seobu-Ro, Jangan-Gu, Suwon, Gyeong Gi-Do, 16419, Republic of Korea
E-mail:
A simple, green, and ultra-fast one-pot supercritical ethanol (scEtOH) route was developed to synthesize tin sulfide.reduced graphene oxides (SnS-RGOs) by the simultaneous reduction of GO and the heterogeneous nucleation and growth of SnS nanosheets on the basal plane of RGO. The SnS.RGO composites exhibited a mesoporous structure with porosity up to 63%. When tested as an anode in lithium-ion batteries, the SnS.RGO composite with 44 wt% SnS loading delivered high reversible capacity of 613 mAh g-1 at 50 mA g-1 after 100 cycles and high rate capacity of 198 mAh g-1 at a high charge-discharge rate of 1 A g-1.
Keywords:Supercritical alcohol;Tin sulfide;Reduced graphene oxide;Composites;Lithium-ion batteries
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