화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.35, No.3, 684-693, March, 2018
Binary semiconductor oxide nanoparticles on graphene oxide (CdO/CeO2/RGO) for the treatment of hazardous organic water pollutants
E-mail:
CdO/CeO2/RGO was prepared by a hydrothermal process. The physical properties of CdO/CeO2/RGO have been investigated by FTIR, XRD, DRS, TEM, SEM and EDX. CdO/CeO2/RGO was used for sonocatalytic degradation of Ibuprofen (IBP), Rodamin B (RhB) and Methyl orange (MO) under ultrasonic irradiation. The catalytic properties of CdO/CeO2/RGO were evaluated with the reduction of 4-nitrophenol (4-NP) into 4-aminophenol (4-AP) by NaBH4. The highest degradation efficiency of IBP in presence of K2S2O8 (91%), RhB (97%) and MO (85%) was observed within 80, 150 and 150 min after the beginning of the reaction, respectively. The reduction efficiency of 4-NP was 79% within reaction time of 70min. Compared to the reduced graphene oxide (RGO) and CdO/CeO2 nanoparticles, CdO/ CeO2/RGO exhibits excellent sonocatalysis on degradation of IBP, azo dyes and catalysis activity on reduction of 4-NP.
  1. Tu YJ, You CF, Chang CK, Wang SL, Chan TS, Chem. Eng. J., 225, 433 (2013)
  2. Jiang Y, Sun Y, Liu H, Zhu F, Yin H, Dyes Pigment., 78, 77 (2008)
  3. Merouani S, Hamdaoui O, Saoudi F, Chiha M, Chem. Eng. J., 158(3), 550 (2010)
  4. Abdullah AZ, Ling PY, J. Hazard. Mater., 173(1-3), 159 (2010)
  5. Narayanan KB, Sakthivel N, Bioresour. Technol., 102(22), 10737 (2011)
  6. Georgaki I, Vasilaki E, Katsarakis N, Am. J. Anal. Chem., 5, 518 (2014)
  7. Lu XJ, Yang B, Chen JH, Sun R, J. Hazard. Mater., 161(1), 241 (2009)
  8. Castell JV, Miranda MA, Morera IM, Photochem. Photobiol., 38, 991 (1987)
  9. Gong H, Chu W, Hiu S, Lin AY, Chemosphere, 167, 415 (2017)
  10. Ca G, Valeria P, Brunella P, Sergio C, J. Pharm Biomed Anal., 30, 499 (2002)
  11. Madhavan J, Maruthamuthu P, Murugesan S, Anandan S, Appl. Catal. C: Environ., 83, 8 (2008)
  12. Ziylan A, Dogan S, Agopcan S, KidakV R, Environ. Sci. Pollut. Res., 21, 5929 (2014)
  13. Wang J, Lv Y, Zhang L, Liu B, Jiang R, Han G, Ultrason. Sonochem., 17, 642 (2010)
  14. Zhang WB, Xiao XM, An TC, Song ZG, Fu JM, Sheng GY, Cui MC, J. Chem. Technol. Biotechnol., 78(7), 788 (2003)
  15. Chartrin P, Environ. Sci. Technol., 34, 3474 (2000)
  16. Naik B, Hazra S, Prasad YS, Ghosh NN, Catal. Commun., 12, 1104 (2011)
  17. Rawtani D, Agrawal YK, Rev. Adv. Mater. Sci., 30, 282 (2012)
  18. Naraginti S, Bernard F, Radhakrishnan A, Sivakumar A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 135, 814 (2015)
  19. Chianese S, Iovino P, Canzano S, Prisciandaro M, Chianese S, Iovino P, Canzano S, Prisciandaro M, Desalin. Water Treat., 3994, 1 (2016)
  20. Lei ZD, Wang JJ, Wang L, Yang XY, Xu G, Tang L, J. Hazard. Mater., 312, 298 (2016)
  21. Lei ZHU, Ghosh T, Park C, Zeda M, Won-chun OH, Chinese J. Catal., 33, 1276 (2012)
  22. Ahmad M, Ahmed E, Hong ZL, Ahmed W, Elhissi A, Khalid NR, Ultrason. Sonochem., 21, 761 (2014)
  23. Thangavel S, Raghavan N, Kadarkarai G, Kim S, Venugopal G, Ultrason. Sonochem., 24, 123 (2015)
  24. Saharan P, Ram G, Lata S, Mehta SK, Mor S, Ultrason. Sonochem., 22, 317 (2015)
  25. Lin SS, Weng HS, Appl. Catal. A: Gen., 118(1), 21 (1994)
  26. Chang D, Chen I, Chen M, Lin S, Chemosphere, 52, 943 (2003)
  27. Bhargava SK, Tardio J, Prasad J, Foger K, Akolekar DB, Grocott SC, Ind. Eng. Chem. Res., 45(4), 1221 (2006)
  28. Li H, Gui X, Ji C, Li P, Li Z, Zhang L, Shi E, Zhu K, Wei J, Nano Res., 5, 265 (2012)
  29. Xu TG, Zhang LW, Cheng HY, Zhu YF, Appl. Catal. B: Environ., 101(3-4), 382 (2011)
  30. Joshi BN, Yoon H, Na S, Choi J, Yoon SS, Ceram. Int., 40, 3647 (2014)
  31. Priyadharsan A, Vasanthakumar V, Karthikeyan S, Raj V, Shanavas S, Anbarasan PM, J. Photochem. Photobiol. A-Chem., 346, 32 (2017)
  32. Shanavas S, Priyadharsan A, Vasanthakumar V, Arunkumar A, Anbarasan PM, Bharathkumar S, J. Photochem. Photobiol. A-Chem., 340, 96 (2017)
  33. Lashanizadegan M, Mirzazadeh H, J. Ceram. Process. Res., 13, 389 (2012)
  34. Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS, ACS Nano., 5, 3333 (2011)
  35. Sahoo PK, Panigrahy B, Bahadur D, RSC Adv., 4, 48563 (2014)
  36. Kamat PV, Chem. Rev., 93, 267 (1993)
  37. De Faria AF, Martinez DST, Meira SMM, de Moraes ACM, Brandelli A, Filho AGS, Alves OL, Colloids Surf. B: Biointerfaces, 113, 115 (2014)
  38. Farahmandjou M, Zarinkamar M, Mater., 48, 5 (2015)
  39. Oh S, Shin WS, Kim HT, Environ. Sci. Pollut. Res., 23, 22882 (2016)
  40. Paul J, Naik DB, Bhardwaj YK, Varshney L, Radiat. Phys. Chem., 100, 38 (2014)
  41. Ince NH, Tezcanli G, Belen RK, Apikyan IG, Appl. Catal. B: Environ., 29(3), 167 (2001)
  42. Nam SN, Han SK, Kang JW, Choi H, Ultrason. Sonochem., 10, 139 (2003)
  43. Raevskaya AE, Stroyuk AL, Kuchmiy SY, J. Colloid Interface Sci., 302(1), 133 (2006)
  44. Murali KR, Swaminathan V, Trivedi DC, Sol. Energy Mater. Sol. Cells, 81(1), 113 (2004)
  45. Matthews RW, J. Phys. Chem., 91, 3328 (1987)
  46. Petrier C, Jeunet A, Luche JL, Reverdy G, J. Am. Chem. Soc., 114, 3148 (1992)
  47. Kaur M, Muthe KP, Despande SK, Choudhury S, Singh JB, Verma N, Gupta SK, Yakhmi JV, J. Cryst. Growth, 289(2), 670 (2006)
  48. Xiao-jun C, Han-hong XU, Yu-jian W, Shan HU, Zhi-xiang Z, Yao-mou Z, Agric. Sci. China, 6, 458 (2007)
  49. Umemura SI, Yumita N, Umemura K, Nishigaki R, Cancer Chemother. Pharmacol., 43, 389 (1999)