화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.60, 237-249, April, 2018
DOI10.1016/j.jiec.2017.11.010  Export Citation
Synthesis and characterization of magnetic poly(acrylonitrile-coacrylic acid) nanofibers for dispersive solid phase extraction and pre-concentration of malachite green from water samples
Nafiseh Sabzroo1, Tahereh Rohani Bastami1, †, Majid Karimi2, Tahereh Heidari3, Shilpi Agarwal4, and Vinod Kumar Gupta4, 5, †
  • 1Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan 94771-67335, Iran
  • 2Department of Polymerization, Faculty of Sciences, Iran Polymer and Petrochemical Institute, Tehran 14975-112, Iran
  • 3Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, 91779, Iran
  • 4Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa
  • 5King Abdulaziz University, Jeddah, Saudi Arabia
E-mail:,
This research describes the development of a new design of nanosorbents, magnetic poly(acrylonitrile- co-acrylic acid) (PAN-co-AA) nanofibers, for the pre-concentration of malachite green (MG) residues in water samples via dispersive magnetic solid phase extraction (d-MSPE) technique. After preconcentration, the spectrophotometric method was used to determine MG. Magnetic PAN-co-AA nonwoven nanofibers was fabricated by the optimized electrospinning technique after optimization of electrospinning conditions. According to the results, increasing magnetic nanoparticles (MNPs) into polymeric matrix led to significant reduction of fiber diameter from 360 to 70 nm. This change was associated with an increase in nanofibers surface area (from 9.66 m2 g-1 to 12.09 m2 g-1). Fabricated magnetic nanofibers demonstrated suitable magnetic properties (3.6 emu g-1), so it can be used for magnetic separation and easy extraction techniques. In the following step, magnetic PAN-co-AA nanofibers (MNFs) were used to determine MG in aquatic samples. The influence of different parameters on extraction was investigated and optimized to improve the extraction efficiency of MG. The calibration curve was linear in the range of 0.3-1.8 mg L-1 of MG with R2 = 0.9911. The detection limit, based on three times the standard deviation of the blank, was 0.03 mg L-1. The relative standard deviation (RSD) for 1, 1.5 and 1.8 mg L-1 of MG was 4.31%, 6.86% and 7.68% (n = 6), respectively. MG was analyzed in different water samples (urban, mineral and river waters) using the proposed method. The recoveries were 95.83-103.3% with an RSD of less than 8%. The results showed that MNFs were suitable for pre-concentration and determination of trace amount of MG in wastewater samples.
Keywords:Electrospinning;Magnetic nanofibers;Poly(acrylonitrile-co-acrylic acid);Dispersive magnetic solid phase extraction;Malachite green
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