CO2-responsive smart wormlike micelles based on monomer and “pseudo” gemini surfactant

Xuepeng Wu; Yongping Huang; Sisi Fang; Caili Dai; Hao Li; Zhongliang Xu; Mingwei Zhao

Journal of Industrial and Engineering Chemistry, Vol.60, 348-354, April, 2018

DOI10.1016/j.jiec.2017.11.021 Export Citation

CO2-responsive smart wormlike micelles based on monomer and “pseudo” gemini surfactant

Xuepeng Wu, Yongping Huang, Sisi Fang, Caili Dai^†, Hao Li, Zhongliang Xu, and Mingwei Zhao^†

School of Petroleum Engineering, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, China

E-mail:,

CO2-responsive wormlike micelles based on monomer erucic acid 3-(N,N-dimethylamino)propylamide (EADP) with or without sodium salicylate (NaSal) in aqueous solution were studied and compared with “pseudo” gemini system. The “pseudo” gemini system were formed by a mixture of EADP and maleic acid (MA) with molar ratio between 2:1-1:1. Different morphological transformations of microstructures in response to EADP concentrations, additives and CO2 stimuli were further investigated in these systems, the wormlike micelle or vesicles can be obtained. The mechanism of these transitions were further investigated by rheology, cryo-TEM and DFT calculation, the results showed that the mechanism behind this transition involved reversible reaction of CO2 with EADP. The mechanism in this research may give further evidence to the self-assembly of CO2-responsive surfactants.

Keywords:CO2-responsive;Smart wormlike micelles;“Pseudo” gemini surfactant. Mechanism

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[Referenced By]

[1] Ma XJ, Zhang YB, Zhang YF, Peng C, Che YK, Zhao JC, Adv. Mater., 27(47), 7746 (2015)

[2] Solomon MJ, Nature, 464, 496 (2010)

[3] Weiss RG, J. Am. Chem. Soc., 136(21), 7519 (2014)

[4] Chu Z, Dreiss CA, Feng Y, Chem. Soc. Rev., 42, 7174 (2013)

[5] Menger FM, Angew. Chem.-Int. Edit., 39, 1906 (2000)

[6] Chu Z, Feng Y, Chem. Commun., 47, 7191 (2011)

[7] Padoan G, de Givenchy ET, Zaggia A, Amigoni S, Darmanin T, Conte L, Guittard F, Soft Matter, 9, 8992 (2013)

[8] Chu Z, Feng Y, Chem. Commun., 46, 9028 (2010)

[9] Rubio J, Alfonso I, Burguete MI, Luis SV, Soft Matter, 7, 10737 (2011)

[10] Fischer P, Rehage H, Langmuir, 13(26), 7012 (1997)

[11] Song AX, Hao JC, J. Colloid Interface Sci., 353(1), 231 (2011)

[12] Wu X, Wu Y, Yang S, Zhao M, Gao M, Li H, Dai C, Soft Matter, 12, 4549 (2016)

[13] Akram M, Bhatt IA, Kabir-ud-Din, J. Phys. Chem. B, 119(8), 3499 (2015)

[14] Zou J, Jafr G, Themistou E, Yap Y, Wintrob ZA, Alexandridis P, Ceacareanu AC, Cheng C, Chem. Commun., 47, 4493 (2011)

[15] Willerich I, Grohn F, Angew. Chem.-Int. Edit., 49, 8104 (2010)

[16] Lin Y, Qiao Y, Yan Y, Huang J, Soft Matter, 5, 3047 (2009)

[17] Liang C, Harjani JR, Robert T, Rogel E, Kuehne D, Ovalles C, Sampath V, Jessop PG, Energy Fuels, 26(1), 488 (2012)

[18] He L, Lin F, Li X, Sui H, Xu Z, Chem. Soc. Rev., 44, 5446 (2015)

[19] Shi HF, Wang Y, Fang B, Talmon Y, Ge W, Raghavan SR, Zakin JL, Langmuir, 27(10), 5806 (2011)

[20] Black JW, Jennings MC, Azarewicz J, Paniak TJ, Grenier MC, Wuest WM, Minbiole KP, Bioorg. Med. Chem. Lett., 24, 99 (2014)

[21] Jessop PG, Mercer SM, Heldebrant DJ, Energy Environ. Sci., 5, 7240 (2012)

[22] von Berlepsch H, Harnau L, Reineker P, J. Phys. Chem. B, 102(39), 7518 (1998)

[23] Zhao L, Wang K, Xu L, Liu Y, Zhang S, Li Z, Yan Y, Huang J, Soft Matter, 8, 9079 (2012)

[24] Zhang Y, Feng Y, Wang J, He S, Guo Z, Chu Z, Dreiss CA, Chem. Commun., 49, 4902 (2013)

[25] Pernia LM, Torti A, Riedinger A, La FR, Petti D, Cingolani R, Bertacco R, Pellegrino T, ACS Nano, 6, 10535 (2012)

[26] Jiang L, Wang K, Ke F, Liang D, Huang J, Soft Matter, 5, 599 (2009)

[27] Zhang Y, Chu Z, Dreiss CA, Wang Y, Fei C, Feng Y, Soft Matter, 9, 6217 (2013)

[28] Yan Q, Zhou R, Fu C, Zhang H, Yin Y, Yuan J, Angew. Chem.-Int. Edit., 50, 4923 (2011)

[29] Jessop PG, Heldebrant DJ, Xiaowang L, Eckert CA, Liotta CL, Nature, 436, 1102 (2005)

[30] Yingxin L, Jessop PG, Michael C, Eckert CA, Liotta CL, Science, 313, 958 (2006)

[31] Yan Q, Zhao Y, Chem. Commun., 50, 11631 (2014)

[32] Sonu, Tiwari AK, Saha SK, Ind. Eng. Chem. Res., 52(17), 5895 (2013)

[33] Feng Y, Chu Z, Soft Matter, 11, 4614 (2015)

[34] Zhang YM, Feng YJ, Wang YJ, Li XL, Langmuir, 29(13), 4187 (2013)

[35] Chu Z, Feng Y, ACS Sustain. Chem. Eng., 1, 75 (2012)

[36] Oda R, Narayanan J, Hassan PA, Manohar C, Salkar RA, Kern F, Candau SJ, Langmuir, 14(16), 4364 (1998)

[37] Dreiss CA, Soft Matter, 3, 956 (2007)

[38] Wei XL, Ping AL, Du PP, Liu J, Sun DZ, Zhang QF, Hao HG, Yu HJ, Soft Matter, 9, 8454 (2013)

[39] Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Mennucci B, Petersson GA, et al., Gaussian, Inc., Wallingford, CT, 2009.