화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.4, 1009-1018, April, 2018
DOI10.1007/s11814-017-0286-8  Export Citation
Change of band-gap position of MTiO2 particle doped with 3d-transition metal and control of product selectivity on carbon dioxide photoreduction
Jeong Yeon Do, Junyeong Kim, Yeju Jang, Youn-Kyoung Baek1, and Misook Kang†
  • Department of Chemistry, College of Natural Sciences, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea
  • 1Powder & Ceramics Division, Korea Institute of Materials Science, Changwon 51508, Korea
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This study attempted to obtain various products from carbon dioxide photoreduction using TiO2 catalysts doped with different transition metals of Mn, Fe, Co, Ni, Cu, and Zn (MTiO2). The band-gaps of MTiO2 catalysts decreased compared to pure TiO2, except for ZnTiO2. The intensities in photoluminescence curves, which can predict the recombination of excited electrons and holes, were weaker in MTiO2 catalysts than that of pure TiO2. The products obtained from carbon dioxide photoreduction were strongly related to the redox potential of carbon dioxide and the locations of band-gaps of MTiO2 catalysts. Methane was predominantly obtained in pure TiO2, FeTiO2, and NiTiO2 catalysts, and methanol and carbon monoxide were selectively produced in the CuTiO2 and ZnTiO2 catalysts, respectively. This result suggests that the desired product from carbon dioxide photoreduction can be selectively synthesized by doping certain metals.
Keywords:MTiO2;3d-Transition Metal;Carbon Dioxide Photoreduction;Methane;Carbon Monoxide;Methanol
  1. Wilk A, Wieclaw-Solny L, Tatarczuk A, Krotki A, Spietz T, Chwoła T, Korean J. Chem. Eng., 34(8), 2275 (2017)
  2. Cui Z, Fan J, Duan H, Zhang J, Xue Y, Tan Y, Korean J. Chem. Eng., 34(1), 29 (2017)
  3. Huang H, Lin J, Zhu G, Weng Y, Wang X, Fu X, Long J, Angew. Chem.-Int. Edit., 55, 8314 (2016)
  4. Xie S, Zhang Q, Liu G, Wang Y, Chem. Commun., 52, 35 (2016)
  5. He Z, Wen L, Wang D, Xue Y, Lu Q, Wu C, Chen J, Song S, Energy Fuels, 3982, 28 (2014)
  6. Nahar S, Zain MFM, Kadhum AAH, Hasan HA, Hasan MR, Materials, 629, 10 (2017)
  7. Zalfani M, Hu ZY, Yu WB, Mahdouani M, Bourguiga R, Wu M, Li Y, Van Tendeloo G, Djaoued Y, Su BL, Appl. Catal. B: Environ., 205, 121 (2017)
  8. Yang Y, Zhang T, Le L, Ruan X, Fang P, Pan C, Xiong R, Shi J, Wei J, Sci. Rep., 4, 7045 (2014)
  9. Zhao H, Pan F, Li Y, J. Materiomics, 3, 17 (2017)
  10. Im YH, Lee JH, Kang MS, Korean J. Chem. Eng., 34(6), 1669 (2017)
  11. Zhang M, Wu J, Lu DD, Yang J, Int. J. Photoenergy, 2013, 1 (2013)
  12. Ansari SA, Khan MM, Ansari MO, Cho MH, New J. Chem., 40, 3000 (2016)
  13. Pesci FM, Wang G, Klug DR, Li Y, Cowan AJ, J. Phys. Chem. C, 117, 25837 (2013)
  14. Zhang K, Park JH, J. Phys. Chem. Lett., 8, 199 (2017)
  15. Lee JH, Lee H, Kang M, Mater. Lett., 178, 316 (2016)
  16. Park M, Kwak BS, Jo SW, Kang M, Energy Conv. Manag., 103, 431 (2015)
  17. Dvoranova D, Brezova V, Mazur M, Malati MA, Appl. Catal. B: Environ., 37(2), 91 (2002)
  18. Sakthivel S, Kisch H, ChemphysChem, 4, 487 (2003)
  19. Yang K, Dai Y, Huang B, Whang MH, J. Phys. Chem. C, 113, 2624 (2009)
  20. Ohno T, Akiyoshi M, Umebayashi T, Asai K, Mitsui T, Matsumura M, Appl. Catal. A: Gen., 265(1), 115 (2004)
  21. Protti S, Albini A, Serpone N, Phys. Chem. Chem. Phys., 16, 19790 (2014)
  22. Low J, Yu J, Ho W, J. Phys. Chem. Lett., 6, 4244 (2015)
  23. Kim HS, Kim D, Kwak BS, Han GB, Um MH, Kang M, Chem. Eng. J., 243, 272 (2014)
  24. Kwak BS, Kang M, Appl. Surf. Sci., 337, 138 (2015)
  25. Ge J, Ping Y, Liu G, Qiao G, Kim EJ, Wang M, Mater. Lett., 181, 216 (2016)
  26. Burton AW, Ong K, Rea T, Chan IY, Microporous Mesoporous Mater., 117, 75 (2009)
  27. Park GO, Shon JK, Kim YH, Kim JM, J. Nanosci. Nanotechnol., 15, 2441 (2015)
  28. Deng X, Matranga C, J. Phys. Chem. C, 113, 11104 (2009)
  29. Jiang ZJ, Jiang Z, Sci. Rep., 6, 27081 (2016)
  30. Muruganandham M, Suri RPS, Sillanpaa M, Lee GJ, Wu JJ, Electron. Mater. Lett., 12, 693 (2016)
  31. Wu F, Banerjee S, Li HF, Myung Y, Banerjee P, Langmuir, 32(18), 4485 (2016)
  32. Tian H, Fan H, Dong G, Ma L, Ma J, RSC Adv., 6, 109091 (2016)
  33. Fang J, Shi F, Bu J, Ding J, Xu S, Bao J, Ma Y, Jiang Z, Zhang W, Gao C, Huang W, J. Phys. Chem. C, 114, 7940 (2010)
  34. Benkoula S, Sublemontier O, Patanen M, Nicolas C, Sirotti F, Naitabdi A, Gaie-Levrel F, Antonsson E, Aureau D, Ouf FX, Wada SI, Etcheberry A, Ueda K, Miron C, Sci. Rep., 5, 15088 (2015)
  35. Sun H, Biedermann L, Bond TC, Geophys. Res. Lett., 34, 17813 (2007)
  36. Pena-Flores J, Palomec-Garfias AF, Marquez-Beltran C, Sanchez-Mora E, Gomez-Barojas E, Perez-Rodriguez F, Nanoscale Res. Lett., 9, 499 (2014)
  37. Chae J, Kang M, J. Power Sources, 196(8), 4143 (2011)
  38. Santos RDS, Faria GA, Giles C, Leite CAP, Barbosa HDS, Arruda MAZ, Longo C, Appl. Mater. Interf., 4, 5555 (2012)
  39. Ghasemi S, Rahimnejad S, Setayesh SR, Rohani S, Gholami MR, J. Hazard. Mater., 172(2-3), 1573 (2009)
  40. Hori Y, Modern Aspect Electrochem., 42, 89 (2008)
  41. Chen JW, Falivene L, Caporaso L, Cavallo L, Chen EYX, J. Am. Chem. Soc., 138(16), 5321 (2016)
  42. Saeidi S, Amin NAS, Rahimpour MR, J. CO2 Utilization, 5, 66 (2014)