화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.61, 19-27, May, 2018
DOI10.1016/j.jiec.2017.11.042  Export Citation
Characterization of zinc sulfide species on smithsonite surfaces during sulfidation processing: Effect of ammonia liquor
Shaojun Bai1, 2, Chunlong Li1, 2, †, Xiangyu Fu1, 2, Jian Liu1, 2, and Shuming Wen1, 2, †
  • 1Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
  • 2State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
E-mail:,
The interaction between sulfide-ion species and smithsonite surfaces in the absence with and without ammonia liquor was investigated. The results of zeta potential and sulfide ion adsorption indicated that NH3 H2O addition promoted the transfer of sulfur in the pulp solutions onto the smithsonite surfaces. Time-of-flight secondary ion mass spectrometry and X-ray photo-electron spectroscopy analysis indicated that the zinc sulfide species was composed of zinc monosulfide and zinc polysulfide and was reinforced by NH3 H2O addition. The distribution ratio of polysulfide in the whole S species increased. The results shed light on reinforcement of the smithsonite sulfidation mechanism with ammonia liquor addition.
Keywords:Smithsonite;Sulfidation processing;Ammonia liquor;Zinc sulfide species;Reinforce
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