Journal of Industrial and Engineering Chemistry, Vol.61, 87-96, May, 2018
Design of ternary hybrid ATO/g-C3N4/TiO2 nanocomposite for visible-light-driven photocatalysis
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Antimony-doped tin oxide (ATO) nanoparticles with an average size of ~8 nm were prepared by co-precipitation and subsequent heat-treatment. A series of ATO/g-CN/TiO2 composites with various ATO contents were successfully prepared by sol.gel method. The composites were characterized using N2 adsorption/desorption (BET), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FTIR). The results indicated that the highest photocatalytic performance is obtained with the incorporation of ATO and g-CN nanoparticles with TiO2. BET surface area, PL spectra, and CV measurements were presented to further study the mechanism of the photoactivity. The superior performance of the ATO/g-CN/TiO2 nanocomposite photocatalyst may be attributed to the high surface area charge-carrier transport medium, a higher carrier transfer rate and lower recombination rate.
Keywords:Antimony-doped tin oxide (ATO);Graphitic carbon nitride (g-CN);Photocatalyst;Methylene blue (MB);Titanium dioxide (TiO2)
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