화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.61, 427-436, May, 2018
DOI10.1016/j.jiec.2017.12.042  Export Citation
Reaction network of the chloromethane conversion into light olefins using a HZSM-5 zeolite catalyst
Monica Gamero, Beatriz Valle, Pedro Castaño†, Andrés T. Aguayo, and Javier Bilbao
  • Department of Chemical Engineering, University of the Basque Country (UPV/EHU), P.O. Box 644, 48080. Bilbao, Spain
E-mail:
The second step of chlorine-mediated methane valorization into hydrocarbons has been investigated using a HZSM-5 zeolite catalyst. A parametric study has enabled to set the reaction network, which is dominated by the dual cycle mechanism and secondary reactions of light olefins. This network explains the formation of methane, light olefins, C5+ aliphatics, paraffins, aromatics and coke. Under the optimal conditions, the light olefin selectivity is >70%, of which >40% corresponds to propylene. Coke is originated in the zeolite micropores and then grows within the matrix meso- and macropores.
Keywords:Methane;Chloromethane;Light olefins;HZSM-5 zeolite;Hydrocarbon pool;Dual cycle mechanism
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