Acid-treated bentonite-supported Ni catalysts were prepared using a microwave-assisted drying process, characterized and used for the hydrogenation of nitrobenzene to aniline. Microwave-assisted drying of the catalyst reduced the drying time from 3h with a traditional heating method to 10min; after drying by microwave irradiation, the acid-treated bentonite-supported Ni catalysts were more stable due to a smaller crystallite size, a higher dispersion of metallic Ni and stronger interactions between Ni and the acid-treated bentonite support than the traditional drying method. Catalytic studies conducted at 300 degrees C with a nitrobenzene liquid hourly space velocity of 3.6mLg(-1)h(-1) and a H-2 gas hourly space velocity of 4,800mLg(-1)h(-1) indicated that the catalyst prepared using the microwave heating method maintained a nitrobenzene conversion of >99.9% with an aniline selectivity >93% during a 60-h reaction. In addition, the catalyst dried using a traditional method only functioned for 16h.