Heteroatom doping is a feasible approach to adjust catalytic performance of the HER catalysts. In this work, we report a design of Fe-doped Co9S8 nanosheets grown on carbon cloth (Fe-Co9S8 NSs/CC) as a hydrophilic 3D monolithic electrocatalyst for efficient hydrogen evolution under all pH. The water contact angle and electrochemical measurements proved that the resultant material was hydrophilic for its nano hierarchitectures and dopant Fe enhanced the catalytic capability of singular Co9S8. In 1.0M KOH, the Fe-Co9S8 NSs/CC possessed a relatively small Tafel slope (95.3 mV dec(-1)) and required the overpotential of 83 mV to achieve 10 mA cm(-2). To drive the same current density, the overpotentials were 65 and 192mV in 0.5 M H2SO4 and 1.0M PBS, respectively. Meanwhile, it showed good cycle stability and durability over 20 h static test at alkaline and neutral condition. The flexible freestanding catalyst has great potential in practical applications. (C) 2018 Elsevier Ltd. All rights reserved.