The need for eco-friendly fuels has given a fillip to search for new molecules and their cost-effective synthesis. A series of ceria-strontium (CexSr1-xO2; x= 0 to 1) catalysts were prepared by a citric acid assisted sol-gel method. These catalysts were characterized by BET, XRD, SEM-EDAX, ICP-MS, FTIR, NH3-TPD and CO2-TPD techniques and tested for the synthesis of dimethyl carbonate (DMC) in a batch reactor for the transesterification of ethylene carbonate (EC). The activity of the synthesized catalysts was found to be closely related to basic and acidic sites, and the surface area of the catalysts. The catalyst, Ce0.6Sr0.4, showed highest basicity and acidity, and was found to be most effective in the formation of DMC from transesterification of EC. Reactions were carried out by varying the particle size (50-800 mu m) and agitation speed (200-600 rpm) for minimizing the internal mass transfer resistance and the external mass transfer resistance, respectively. Further, Ce0.6Sr0.4 catalyst was used to optimize the reaction conditions such as methanol/EC molar ratio (in the range of 4-12), catalyst dose (in the range of 2-5 wt% of EC), reaction time (in the range of 2-6 h) and temperature (in the range of 100-180 degrees C) for DMC yield and EC conversion. At the optimum conditions of methanol/EC molar ratio of 8, 3 wt% of catalyst, 5 h reaction time and 150 degrees C temperature, the DMC selectivity was 87% and EC conversion of 82%, with a reaction rate of similar to 0.547 mol/L. h (with respect to EC). The reusability of the Ce0.6Sr0.4 catalyst for EC conversion with turn-over frequency and DMC selectivity were also studied.