We report on the thermochemical conversion of inedible crop residues using concentrated solar energy as the source of high-temperature process heat. Experiments were performed using a 5 kW(th) solar packed-bed reactor exposed to radiative fluxes up to 1788 suns. The waste biomass feedstock consisted of unprocessed batches of cotton boll, soybean husk, and black mustard husk and straw, which were pyrolysed and steam-based gasified at nominal temperatures in the range 879-1266 degrees C, yielding high-quality syngas with molar ratios in the range H-2:CO = 1.43-3.25, CO2:CO = 0.28-1.40, and CH4:CO = 0.03-0.28. The solar-to-fuel energy conversion efficiency, defined as the ratio of the heating value of the syngas produced to the solar radiative energy input and the heating value of the feedstock, reached 18%. The heating value of the feedstock was solar-upgraded by 7%, thus outperforming autothermal gasification that typically downgrades by at least 15%. The ash contained 23% potassium. The solar-driven thermochemical process offers a sustainable and efficient path for the conversion of agricultural wastes into valuable fuels and soil fertilizers.