화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.43, No.2, 921-931, 2018
Electrochemical performance assessment of low temperature solid oxide fuel cell with YSZ-based and SDC-based electrolytes
In this work, solid oxide fuel cells (SOFCs) based on different electrolytes, i.e., the yttriastabilized zirconia (YSZ) and the samaria-doped ceria (SDC), were investigated to study their performances at low-temperature operation. The predicted performance of both SOFCs was validated with the experimental results. The verified models were implemented to study the impact of operating conditions, i.e., cell temperature, pressure, thicknesses of cathode, anode, and electrolyte, on their performances. The decrease in the operating temperature from intermediate range (800-900 degrees C) to low range (550-650) degrees C has a considerable effect on the performance of the YSZ-based SOFC as conventional type, which dropped from 0.67-1.40 W/cm(2) to 0.027-0.13 W/cm(2). Under the low operating temperature range, the performance of SDC-based SOFC was superior to that of the YSZ-based SOFC, due to the lower ohmic loss. Nevertheless, the SDC-based SOFC has higher concentration overpotentials than the YSZ-based SOFC. The concentration overpotentials of the SDC-based SOFC can be reduced by the thinner anode and cathode thicknesses. In addition, the SDC-based SOFC at low operating temperature with the pressurized operation could significantly improve its power density, about 20% at 2 bar, which was close to that of YSZ-based SOFC at intermediate temperature of 800 degrees C. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.