Journal of Colloid and Interface Science, Vol.513, 843-851, 2018
Fallen leaves derived honeycomb-like porous carbon as a metal-free and low-cost counter electrode for dye-sensitized solar cells with excellent tri-iodide reduction
Utilizing carbon-based counter electrodes (CEs) in dye-sensitized solar cells (DSSCs) have received much attention in recent times, owing to their low cost, good electrochemical activity, natural abundance and eco-friendly nature. Herein, we have facilely prepared quince leaves derived porous carbon (QLPC) using fallen quince leaves (QLs) and it was used as a cost-effective CE for the fabrication of DSSCs. By means of alkali treatment and pyrolysis process (at different temperatures of 700, 800 and 900 degrees C), the QLs powder undergoes chemical activation and carbonization, which results in a honeycomb-like QLPC with abundant micro/mesopores and large surface area. Simple and straightforward coating of QLPC samples onto fluorine doped tin oxide glass substrates led to improved electrocatalytic activity and good tri-iodide reduction in DSSCs. When the DSSCs were illuminated under 1 sun condition (AM 1.5; 100 mW cm (2)), the device assembled with QLPC-based CE (prepared at 800 degrees C) showed a higher current density of similar to 14.99 mA/cm(2) and power conversion efficiency of similar to 5.52% among the other QLPC-based CEs, which are comparable with the platinum-based CE in DSSCs. This facile process for the preparation of biomass derived carbon-based CE provides an alternative to the noble metal-free CE in DSSCs. (C) 2017 Elsevier Inc. All rights reserved.