Journal of Crystal Growth, Vol.487, 83-86, 2018
Optical study of Tm-doped solid solution (Sc0.5Y0.5)(2)SiO5 crystal
Tm-doped (Sc0.5Y0.5)(2)SiO5 (SYSO) crystals were grown by Czochralski method. The UV-VIR-NIR absorption spectra and the near-infrared emission spectra were measured and analysed by the Judd-Ofelt approach. Temperature influence on both absorption and emission spectra has been determined from the data recorded at room temperature and 10 K. It has been found that the structural disorder resulting from dissimilar ionic radii of Sc3+ and Y3+ in the solid solution (Sc0.5Y0.5)(2)SiO5 crystal brings about a strong inhomogeneous broadening of Tm3+ ions spectra. However, it affects the excited state relaxation dynamics inherent to thulium-doped Y2SiO5 and Sc2SiO5 hosts weakly. (C) 2018 Elsevier B.V. All rights reserved.
Keywords:Characterization;Czochralski method;Single crystal growth;Rare earth compounds;Solid state lasers