The synthesis and energy storage application of hierarchical porous carbons with size ranging from nano-to micrometres has attracted considerable attention all over the world. Exploring eco-friendly and reliable synthesis of hierarchical porous carbons for supercapacitors with high energy density and high power is still of ongoing challenge. In this work, we report the design and synthesis of super-hierarchical porous carbons with highly developed porosity by a stepwise removal strategy for high-rate supercapacitors. The mixed biomass wastes of coconut shell and sewage sludge are employed as raw material. The as-prepared super-hierarchical porous carbons present high surface areas (3003 m(2) g(-1)), large pore volume (2.04 cm(2) g(-1)), appropriate porosity, and outstanding electrochemical performance. The dependence of electrochemical performance on structural, textural, and functional properties of carbons engineered by various synthesis strategies is investigated in detail. Moreover, the as-assembled symmetrical supercapacitor exhibits high energy density of 25.4 Wh kg(-1) at a power density of 225 W kg(-1) and retains 20.7 Wh kg(-1) even at a very high power of 9000 W kg(-1). This work provides an environmentally benign strategy and new insights to efficiently regulate the porosity of hierarchical porous carbons derived from biomass wastes for energy storage applications.