Alginate membranes filled with different metal oxide particles were prepared and the influence of the presence of different amounts of Fe3O4, ZnO, and Ag2O particles on ethanol and water permeation was discussed. Ethanol and water vapour permeation rates were determined using the measuring cell method, and the mass transport coefficients were evaluated. It was found that the highest transport parameters were obtained for membranes with the highest metal oxide content. Furthermore, the highest flux, equal 8.49kgm(-2)h(-1), was obtained for the alginate membrane filled with 15wt% of silver oxide particles, while the greatest selectivity coefficients were noted for membranes containing magnetite. In this case, for the alginate membrane with 15wt% of magnetite content, the selectivity coefficient reached the best value of 108.15.