Advances in Polymer Technology, Vol.14, No.3, 237-242, 1995
THE DISSOLUTION REPRECIPITATION TECHNIQUE APPLIED ON HIGH-DENSITY POLYETHYLENE .1. MODEL RECYCLING EXPERIMENTS
A model dissolution/reprecipitation process is studied for the recycling of high-density polyethylene (HDPE). The process proposed basically comprises dissolution of the plastic in an appropriate solvent, reprecipitation by using a nonsolvent, thorough washing of the material obtained, and drying. The solvent mixtures involved are separated by distillation for further reuse. Toluene/acetone was tried as a potential solvent/nonsolvent pair and proved to be very satisfactory, similarly to the case of recycling low-density polyethylene. Further investigation was focused on the effect of sample history through successive recycling cycles. The recycled grades were evaluated in terms of the following properties: melt flow index (MFI), molecular weight, crystallinity, mechanical performance in tensile mode, and grain size analysis. In all cases the recycled polymer exhibited excellent retention of its properties.