화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.62, 197-208, June, 2018
DOI10.1016/j.jiec.2017.12.058  Export Citation
Tuning the free volume of polynorbornene-based membranes by blending 6FDA-durene to improve H2 permselectivity
Seoyoon Yu, Choong-Sun Lim, and Bongkuk Seo†
  • Center for Chemical Industry Development, Korea Research Institute of Chemical Technology, 45, Jongga-ro, Yugok-dong, Jung-gu, Ulsan 44412, Republic of Korea
E-mail:
Homogeneous blend membranes of polynorbornene and 2,2'-bis(3,4'-dicarboxyphenyl)hexafluoropro- pane dianhydride (6FDA)-durene were prepared to improve H2 permselectivity. The thermal properties and gas permselectivity of membranes with different polynorbornene/6FDA-durene blending ratios were investigated. The structural changes due to blending result in increased permeability derived from an increase in the fractional free volume of polymer blends with increasing glass transition temperature. Moreover, an increase in the 6FDA-durene content in the blends improved gas permeation, diffusivity, and solubility. The prepared blend membranes showed excellent gas permeation properties, namely, high gas permeability for H2 (14-971 Barrer) and high H2/N2 (α = 13-46) and H2/CO (α = 10-29) permselectivities.
Keywords:Gas permeability;Polynorbornene;6FDA-durene;Blend membrane;Fractional free volume
  1. Dorkenoo KD, Pfromm PH, Rezac ME, J. Polym. Sci. B: Polym. Phys., 36(5), 797 (1998)
  2. Haselwander TFA, Heits W, Krugel SA, Wendorff JH, Macromol. Chem. Phys., 197, 3435 (1996)
  3. Haselwander TF, Heitz W, Krugel SA, Wendorff JH, Macromolecules, 30(18), 5345 (1997)
  4. Lee KS, Kim JH, J. Korean Ind. Eng. Chem., 18(5), 483 (2007)
  5. Zhang Y, Shen J, Zhang Q, Xu Z, Yeung KW, Yi C, Adv. Mater., 6, 44 (2014)
  6. Moor JA, Robello DR, Macromolecules, 22, 1084 (1989)
  7. Matsumoto K, Xu P, J. Appl. Polym. Sci., 47, 1961 (1993)
  8. Coleman MR, Koros WJ, J. Membr. Sci., 50, 285 (1990)
  9. Yamamoto H, Mi Y, Stern SA, Clair AKS, J. Polym. Sci. B: Polym. Phys., 28, 2291 (1990)
  10. Ha HT, Nam SW, Hong SA, Membr. J., 9, 63 (1999)
  11. Mannan A, Mukhtar H, Murugesan T, Nasir R, Mohshim DR, Mushtaq A, Chem. Eng. Technol., 11, 1838 (2013)
  12. Yu SY, Lim CS, Kim JC, Seo BK, Sci. Adv. Mater., 8, 2112 (2016)
  13. Vargas J, Martinez A, Santiago AA, Tlenkopatchev MA, Aguilar-Vega M, Polymer, 48(22), 6546 (2007)
  14. Vargas J, Martinez A, Santiago AA, Tlenkopatchev MA, Gavino R, Aguilar-Vega M, J. Fluor. Chem., 130, 162 (2009)
  15. Vargas J, Santiago AA, Cruz-Morales JA, Tlenkopatchev MA, de Lys T, Lopez-Gonzalez M, Riande E, Macromol. Chem. Phys., 214, 2607 (2013)
  16. Vargas J, Santiago AA, Tlenkopatchev MA, Lopez-Gonzalez M, Riande E, J. Membr. Sci., 361(1-2), 78 (2010)
  17. Dorkenoo KD, Pfromm PH, Rezac ME, J. Polym. Sci. B: Polym. Phys., 36(5), 797 (1998)
  18. Yampolskii YP, Bespalova NB, Finkelshtein ES, Bondar VI, Popov AV, Macromolecules, 27(10), 2872 (1994)
  19. Pozuelo J, Lopez-Gonzalez M, Tlenkopatchev M, Saiz E, Riande E, J. Membr. Sci., 310(1-2), 474 (2008)
  20. Tlenkopatchev MA, Vargas J, Lopez-Gonzalez MD, Riande E, Macromolecules, 36(22), 8483 (2003)
  21. Vargas J, Santiago AA, Tlenkopatchev MA, Gavino R, Laguna MF, Lopez-Gonzalez M, Riande E, Macromolecules, 40(3), 563 (2007)
  22. Diaz K, Vargas J, Castillo LFD, Tlenkopatchev MA, Aguilar-Vega M, Macromol. Chem. Phys., 206, 2316 (2005)
  23. Cruz-Morales JA, Vargas J, Santiago AA, Vasquez-Garcia SR, Tlenkopatchev MA, de Lys T, Lopez-Gonzalez M, High Perform. Polym., 28, 1246 (2016)
  24. Contreras AP, Tlenkopatchev MA, Ogawa T, Nakagawa T, Polym. J., 34, 49 (2002)
  25. Tetsuka H, Hagiwara M, Kaita S, Polym. J., 43, 97 (2011)
  26. Finkelshtein ES, Bermeshev MV, Gringolts ML, Starannikova LE, Yampolskii YP, Russ. Chem. Rev., 80, 341 (2011)
  27. Jou JH, Huang PT, Polymer, 33, 1218 (1992)
  28. Chung TS, Kafchinski ER, Polymer, 37(9), 1635 (1996)
  29. Ree M, Shin TJ, Kim SI, Woo SH, Yoon DY, Polymer, 39(12), 2521 (1998)
  30. Zuo M, Takeichi T, Polymer, 40(18), 5153 (1999)
  31. Liu HB, Simone CD, Katiyar PS, Scola DA, Int. J. Adhes. Adhes., 25, 219 (2005)
  32. Yun SJ, Im HG, Kim JH, Polymer, 34, 97 (2010)
  33. Powell CE, Qiao GG, J. Membr. Sci., 279(1-2), 1 (2006)
  34. Koros WJ, Fleming GK, Jordan SM, Kim TH, Hoehn HH, Prog. Polym. Sci, 13, 339 (1988)
  35. Koros WJ, Hellums MW, Fluid Phase Equilib., 53, 339 (1989)
  36. Mi Y, Stern SA, Trohalaki S, J. Membr. Sci., 77, 41 (1993)
  37. Hirayama Y, Yoshinaga T, Kusuki Y, Ninomiya K, Sakakibara T, Tamari T, J. Membr. Sci., 111(2), 169 (1996)
  38. Ohya H, Kudryavsev VV, Semenova SI, Polyimide Membranes: Applications, Fabrications, and Properties, Gordon and Breach, Tokyo, 1996.
  39. Love JA, Morgan JP, Trnka TM, Grubbs RH, Angew. Chem.-Int. Edit., 41, 4035 (2002)
  40. Kammakakam I, Nam SY, Kim TH, RSC Adv., 6, 31083 (2016)
  41. Bondi A, Physical Properties of Molecular Crystals, Liquids and Glasses, Wiley, New York, 1968.
  42. van Krevelen DW, Properties of Polymers, Elsevier, New York, 1990.
  43. Clarizia G, Algieria C, Drioli E, Polymer, 45(16), 5671 (2004)
  44. Yang SY, Park CE, Jung MS, Polymer, 44(11), 3243 (2003)
  45. Min UK, Chang JH, Polymer, 34, 495 (2010)
  46. Chan SS, Chung TS, Liu Y, Wang R, J. Membr. Sci., 218(1-2), 235 (2003)
  47. Weiss RA, Ghebremeskel Y, Charbonneau L, Polymer, 41(9), 3471 (2000)
  48. Rana D, Kim HL, Kwag H, Choe S, Polymer, 41(19), 7067 (2000)
  49. Rana D, Cho K, Woo T, Lee BH, Choe S, J. Appl. Polym. Sci., 74(5), 1169 (1999)
  50. Rana D, Lee CH, Cho K, Lee BH, Choe S, J. Appl. Polym. Sci., 69(12), 2441 (1998)
  51. Pan FS, Peng FB, Lu LY, Wang JT, Jiang ZY, Chem. Eng. Sci., 63(4), 1072 (2008)
  52. Cohen MH, Turnbull DJ, J. Chem. Phys., 31, 1164 (1959)
  53. Lee WM, Polym. Eng. Sci., 20, 65 (1980)
  54. Rana D, Bag K, Bhattacharyya SN, Mandal BM, J. Polym. Sci. B: Polym. Phys., 38(3), 369 (2000)
  55. Rana D, Mandal BM, Bhattacharyya SN, Macromolecules, 29(5), 1579 (1996)
  56. Rana D, Mandal BM, Bhattacharyya SN, Polymer, 37(12), 2439 (1996)
  57. Rana D, Mandal BMM, Bhattacharyya SN, Polymer, 34, 1454 (1993)
  58. Bikiaris D, Prinos J, Botev M, Betchev C, Panayiotou C, J. Appl. Polym. Sci., 93(2), 726 (2004)
  59. Rumondor ACF, Ivanisevic I, Bates S, Alonzo DE, Taylor LS, Pharm. Res., 26, 2523 (2009)
  60. Lin HQ, Freeman BD, Macromolecules, 38(20), 8394 (2005)
  61. Freeman BD, Pinnau I, Polym. Membr. Gas Vap. Sep., 733, 1 (2016)
  62. Merkel TC, Bondar VI, Nagai K, Freeman BD, Pinnau I, J. Polym. Sci. B: Polym. Phys., 38(3), 415 (2000)
  63. Van Amerongen GJ, Rubber Chem. Technol., 37, 1065 (1964)
  64. Massman WJ, Atmos. Environ., 32, 1111 (1998)
  65. Lin H, Freeman BD, J. Membr. Sci., 239(1), 105 (2004)
  66. Lin WH, Chung TS, J. Membr. Sci., 186(2), 183 (2001)
  67. Liu Y, Wang R, Chung TS, J. Membr. Sci., 189(2), 231 (2001)
  68. Yan Y, Wang X, Zhang Y, Wang P, Cao X, Zhang J, Corrosion Sci., 73, 123 (2013)
  69. Shieh JJ, Chung TS, J. Polym. Sci. B: Polym. Phys., 37(20), 2851 (1999)
  70. Kresse I, Usenko A, Springer J, Privalko V, J. Polym. Sci. B: Polym. Phys., 37(16), 2183 (1999)
  71. Li XG, Kresse I, Springer J, Nissen J, Yang YL, Polymer, 42(16), 6859 (2001)
  72. Song Q, Cao S, Pritchard RH, Ghalei B, Al-Muhtaseb SA, Terentjev EM, Cheetham AK, Sivaniah E, Nat. Commun., 5, 1 (2014)
  73. Shao L, Chung TS, Goh SH, Pramoda KP, J. Membr. Sci., 238(1-2), 153 (2004)
  74. David OC, Gorri D, Nijmeijer K, Ortiz I, Urtiaga A, J. Membr. Sci., 419, 49 (2012)
  75. Vargas J, Martinez A, Santiago AA, Tlenkopatchev MA, Gavino R, Aguilar-Vega M, J. Fluor. Chem., 130, 162 (2009)
  76. Chun BW, Ishizu C, Itatani H, Haraya K, Shindo Y, J. Polym. Sci. B: Polym. Phys., 32(6), 1009 (1994)
  77. Chan SS, Chung TS, Liu Y, Wang R, J. Membr. Sci., 218(1-2), 235 (2003)