화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.62, 250-257, June, 2018
DOI10.1016/j.jiec.2018.01.002  Export Citation
Metal-organic framework-derived hierarchical ZnO/NiO composites: Morphology, microstructure and electrochemical performance
Ping Yang†, Xueling Song, Changchao Jia, and Hsueh-Shih Chen1
  • School of Material Science and Engineering, University of Jinan, Jinan 250022, PR China
  • 1Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan
E-mail:
Hierarchical ZnO/NiO microstructures with different morphologies were synthesized employing bimetallic Zn/Ni MOFs as the precursor. The MOFs with rambutan- and seaweed-like morphologies were produced using terephthalic acid and polyvinylpyrrolidone. The molar ratio of Zn/Ni plays an important role for the microstructure and capacitance performance of samples. In particular, hierarchical ZnO/NiO hollow microspheres and seaweed microflowers were obtained when the molar ratio of Zn/Ni was 1:2 and 1:1, respectively. The seaweed microflowers exhibited larger specific capacitance and higher rate capability. The composition and unique microstructure result in improved ionic and electronic conductivity and rich electroactive sites for the electrochemical reactions.
Keywords:ZnO;NiO;Metal-organic framework;Morphology;Electrochemical
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