화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.62, 302-310, June, 2018
DOI10.1016/j.jiec.2018.01.008  Export Citation
Zn (II) removal by amino-functionalized magnetic nanoparticles: Kinetics, isotherm, and thermodynamic aspects of adsorption
Nahid Ghasemi1, Maryam Ghasemi2, Saleh Moazeni1, Parisa Ghasemi3, Njud S. Alharbi4, Vinod Kumar Gupta4, 5, †, Shilpi Agarwal5, Irina V. Burakova6, and Alexey G. Tkachev6
  • 1Department of Chemistry, Sciences Faculty, Arak Branch, Islamic Azad University, Arak, Iran
  • 2Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran
  • 3Faculty of Engineering Science, Department of Technical College, Tehran University, Tehran, Iran
  • 4Department of Biological Sciences, King Abdulaziz University, Jeddah 21589, Saudi Arabia
  • 5Applied Chemistry Department, University of Johannesburg, Doornfontein Campus, Johannesburg, South Africa
  • 6Tambov State Technical University, 106, Sovetskaya Str., Tambov 392000, Russia, Russian Federation
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In this study, a novel adsorbent, dioctylphetalate triethylenetetraamine magnetic nanoparticles (DOP- TETA-MNP) via a solvent-free procedure were synthesized for the removal of Zn (II) ions from aqueous solution. The morphological and anatomical characterization was investigated by various analytical techniques such as FTIR and SEM. Experimental data from evaluation of various influential parameters such as initial pH (2-7), initial ion concentration (5.20 mg/L), adsorbent dose (0.005-0.040 g), contact time (5-120 min) and temperature (308-333 K) of the solution were carried out using a batch adsorption method. DOP-TETA-MNP can be simply separated from aqueous solution with magnetic separations at low magnetic field. The kinetic data of Zn (II) ions were found to follow the pseudo-second-order kinetic model and the equilibrium data of ions sorption were well described by Langmuir isotherm model. The maximum monolayer sorption capacity of Zn (II) was estimated to be 24.21 mg/g at temperature of 333 K. Thermodynamic analyses show that the adsorption process is exothermic and spontaneous.
Keywords:Dioctylphetalate;Triethylenetetraamine;Magnetic nanoparticles;Removal;Zn (II) ions
  1. Ghasemi M, Javadian H, Ghasemi N, Agarwal S, Gupta VK, J. Mol. Liq., 215, 161 (2016)
  2. Zhu J, Sadu R, Wei S, Chen DH, Haldolaarachchige N, Luo Z, Gomes JA, Young DP, Guo Z, ECS J. Solid State Sci. Technol., 1(1), M1 (2012)
  3. Zhang L, Yu W, Han C, Guo J, Zhang QH, Xie HY, Shao Q, Sun ZG, Guo ZH, J. Electrochem. Soc., 164(9), H651 (2017)
  4. Song B, Wang T, Sun H, Shao Q, Zhao J, Song K, Hao L, Wang L, Guo Z, Dalton Trans., 46, 15769 (2017)
  5. Hu L, Wan J, Zeng G, Chen A, Chen G, Huang Z, He K, Cheng M, Zhou C, Environ. Sci.: Nano, 4, 2018 (2017)
  6. Zeng GM, Wan J, Huang DL, Hu L, Huang C, Cheng M, Xue WJ, Gong XM, Wang RZ, Jiang DN, J. Hazard. Mater., 339, 354 (2017)
  7. Gupta VK, Agarwal S, Tawfik, Saleh A, J. Hazard. Mater., 185, 17 (2011)
  8. Gupta VK, Rastogi A, J. Hazard. Mater., 152(1), 407 (2008)
  9. Wan J, Zeng GM, Huang DL, Hu L, Xu P, Huang C, Deng R, Xue WJ, Lai C, Zhou CY, Zheng KX, Ren XY, Gong XM, J. Hazard. Mater., 343, 332 (2018)
  10. Maheshwari U, Mathesan B, Gupta S, Process Saf. Environ. Protect., 98, 198 (2015)
  11. Foroughi F, Hassanzadeh-Tabrizi SA, Amighian J, Saffar-Teluri A, Ceram. Int., 41, 6844 (2015)
  12. Gupta VK, Pathania D, Singh P, Kumar A, Rathore BS, Carbohydr. Polym., 101, 684 (2014)
  13. Hu L, Zeng GM, Chen GQ, Dong HR, Liu YT, Wan J, Chen AW, Guo Z, Yan M, Wu HP, Yu ZG, J. Hazard. Mater., 301, 106 (2016)
  14. Wan J, Zhang C, Zeng GM, Huang DL, Hu L, Huang C, Wu HP, Wang LL, J. Hazard. Mater., 320, 278 (2016)
  15. Yu G, Lu Y, Guo J, Bafana MAP, Wang X, Qiu B, Jeffryes C, Wei S, Guo Z, Wujcik EK, Adv. Comp. Hybrid Mater. (2017), doi:http://dx.doi.org/10.1007/s42114-017-0004-3.
  16. Ghasemi M, Naushad M, Ghasemi N, Khosravi-fard Y, J. Ind. Eng. Chem., 20(2), 454 (2014)
  17. Gupta VK, Suhas, Nayak A, Agarwal S, Chaudhary M, Tyagi I, J. Mol. Liq., 190, 215 (2014)
  18. Ma YL, Lv L, Guo YR, Fu YJ, Shao Q, Wu TT, Guo SJ, Sun K, Guo XK, Wujcik EK, Guo ZH, Polymer, 128, 12 (2017)
  19. Srivastava V, Sharma YC, Sillanpaa M, Ceram. Int., 41, 6702 (2015)
  20. Wang TQ, Zhang P, Wu DS, Sun MZ, Deng YH, Frost RL, J. Colloid Interface Sci., 443, 65 (2015)
  21. Bao SY, Tang LH, Li K, Ning P, Peng JH, Guo HB, Zhu TT, Liu Y, J. Colloid Interface Sci., 462, 235 (2016)
  22. Krishnan KA, Sreejalekshmi KG, Vimexen V, Dev VV, Ecotoxicol. Environ. Saf., 124, 418 (2016)
  23. Kyzas GZ, Siafaka PI, Pavlidou EG, Chrissafis KJ, Bikiaris DN, Chem. Eng. J., 259, 438 (2015)
  24. Tokoro C, Sakakibara T, Suzuki S, Chem. Eng. J., 279, 86 (2015)
  25. SenthilKumar P, Ramalingam S, Abhinaya RV, Kirupha SD, Vidhyadevi T, Sivanesan S, Can. J. Chem. Eng., 90(4), 973 (2012)
  26. Alvarez-Ayuso E, Garcia-Sanchez A, Querol X, Water Res., 37, 4855 (2003)
  27. Gu H, Zhang H, Ma C, Lyu S, Yao F, Liang C, Yang X, Guo J, Guo Z, Gu J, J. Phys. Chem. C, 121(24), 13265 (2017)
  28. Wang X, Liu X, Yuan H, Liu H, Liu C, Li T, Yan C, Yan X, Shen C, Guo Z, Mater. Des., 139, 372 (2018)
  29. Ghasemi M, Naushad M, Ghasemi N, Khosravi-fard Y, J. Ind. Eng. Chem., 20(4), 2193 (2014)
  30. Zhu J, Chen M, Qu H, Wei H, Guo J, Luo Z, Haldolaarachchige N, Young DP, Wei S, Guo Z, J. Mater. Chem. C, 2, 715 (2014)
  31. Ghaedi M, Hajjati S, Mahmudi Z, Tyagi I, Agarwal S, Maity A, Gupta VK, Chem. Eng. J., 268, 28 (2015)
  32. Huang D, Xue W, Zeng G, Wan J, Chen G, Huang C, Zhang C, Cheng M, Xu P, Water Res., 106, 15 (2016)
  33. Huang D, Hu C, Zeng G, Cheng M, Xu P, Gong X, Wang R, Xue W, Sci. Total Environ., 574, 1599 (2017)
  34. Xue WJ, Huang DL, Zeng GM, Wan J, Zhang C, Xu R, Cheng M, Deng R, J. Hazard. Mater., 341, 381 (2018)
  35. Zhang K, Li GH, Feng LM, Wang N, Guo J, Sun K, Yu KX, Zeng JB, Li T, Guo Z, Wang M, J. Mater. Chem. C, 5, 9359 (2017)
  36. Mahmouda ME, Yakout AA, Hamza KH, Osman MM, J. Ind. Eng. Chem., 25, 207 (2015)
  37. Lagergren S, Kung. Sven. Veten. Hand., 24, 1 (1898)
  38. Huang JN, Cao YH, Shao J, Peng XF, Guo ZH, Ind. Eng. Chem. Res., 56(38), 10689 (2017)
  39. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  40. Qiu B, Xu C, Sun D, Yi H, Guo J, Zhang X, Qu H, Guerrero M, Wang X, Noel N, Luo Z, Guo Z, Wei S, ACS Sustain. Chem. Eng., 2(8), 2070 (2014)
  41. Weber WJ, Morris JC, J. Sanit. Eng. Div., 90, 79 (1964)
  42. Qiu B, Xu C, Sun D, Wei H, Zhang X, Guo J, Wang Q, Rutman D, Guo Z, Wei S, RSC Adv., 4, 29855 (2014)
  43. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  44. Qiu B, Guo J, Zhang X, Sun D, Gu H, Wang Q, Wang H, Wang X, Zhang X, Weeks BL, Guo Z, Wei SG, ACS Appl. Mater. Interfaces, 6(22), 19816 (2014)
  45. Ghasemi M, Khosroshahy MZ, Abbasabadi AB, Ghasemi N, Javadian H, Fattahi M, Powder Technol., 274, 362 (2015)
  46. Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
  47. Zhou Y, Yang M, Wu W, Vasiliev AL, Zhu K, Padture NP, J. Magn. Reson. A, 3, 8178 (2015)
  48. Ghasemi M, Mashhadi S, Asif M, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 213, 317 (2016)
  49. Mashhadi S, Sohrabi R, Javadian H, Ghasemi M, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 215, 144 (2016)
  50. Asgari G, Roshani B, Ghanizadeh G, J. Hazard. Mater., 217-218, 123 (2012)
  51. Ghaedi M, Kokhdan SN, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 136, 141 (2015)
  52. Guzel F, Saygili H, Saygili GA, Koyuncu F, J. Ind. Eng. Chem., 20(5), 3375 (2014)
  53. Amer SI, March/April 1998, https://www.pfonline.com/articles/treating-plating-wastewater.
  54. Kanawade SM, Gaikwad RW, Int. J. Chem. Eng. Appl., 2(3), 199 (2011)
  55. Farazmand A, Orumieh H, Tashayouie H, Water Wastewater, 16(3), 69 (1984)
  56. Tokoro C, Sakakibara T, Suzuki S, Chem. Eng. J., 279, 86 (2015)
  57. Xu P, Zeng G, Huang D, Hu S, Feng C, Lai C, Zhao M, Huang C, Li N, Wei Z, Xie G, Colloids Surf. A: Physicochem. Eng. Asp., 419, 147 (2013)
  58. Mahmouda ME, Yakout AA, Hamza KH, Osman MM, J. Ind. Eng. Chem., 25, 207 (2015)
  59. Islam MA, Benhouria A, Asif M, Hameed BH, J. Taiwan Inst. Chem. Eng., 52, 57 (2015)
  60. Zhou YT, Nie HL, Branford-White C, He ZY, Zhu LM, J. Colloid Interface Sci., 330(1), 29 (2009)
  61. Liu X, Luo J, Zhu Y, Yang Y, Yang S, J. Alloy. Compd., 648, 986 (2015)
  62. Anitha T, Kumar PS, Kumar KS, Environ. Prog. Sustain. Energy, 34(1), 15 (2015)
  63. Rezgui A, Hannachi Y, Guibal E, Boubaker T, Desalin. Water Treat., 56, 2699 (2015)
  64. Muthukrishnaraj A, Manokaran J, Vanitha M, Thiruvengadaravi KV, Baskaralingam P, Balasubramanian N, Desalin. Water Treat., 56, 2485 (2015)
  65. Javadian H, Ghasemi M, Ruiz M, Sastre AM, Hosseini-Asl SM, Masomi M, Ultrason. Sonochem., 40, 748 (2018)
  66. Singh S, Barick KC, Bahadur D, J. Hazard. Mater., 192(3), 1539 (2011)
  67. Ammari TG, Al-Labadi I, Tahboub A, Ghrair A, Process Saf. Environ. Protect., 95, 77 (2015)
  68. Ge F, Li MM, Ye H, Zhao BX, J. Hazard. Mater., 211-212, 366 (2012)
  69. Gupta VK, Kumar S, Singh R, Singh LP, Shoora SK, Sethi B, J. Mol. Liq., 195, 65 (2014)
  70. Karthikeyan S, Gupta VK, Boopathy R, Titus A, Sekaran G, J. Mol. Liq., 173, 153 (2012)
  71. Gupta VK, Singh AK, Kumawat LK, Sens. Actuators B-Chem., 195, 98 (2014)
  72. Saleh TA, Gupta VK, Sep. Purif. Technol., 89, 245 (2012)
  73. Mohammadi N, Khani H, Agarwal S, Gupta VK, J. Colloids Interface Sci., 457 (2011).
  74. Gupta VK, Sethi B, Sharma RA, Agarwal S, Bharti A, J. Mol. Liq., 177, 114 (2013)
  75. Saleh TA, Gupta VK, Adv. Colloid Interface Sci., 211, 92 (2014)
  76. Saleh TA, Agarwal S, Gupta VK, Appl. Catal. B: Environ., 106(1-2), 46 (2011)
  77. Gupta VK, Nayak A, Agarwal S, Environ. Eng. Res., 20(1), 001 (2015)
  78. Gupta VK, Ganjali MR, Norouzi P, Khani H, Nayak A, Agarwal S, Crit. Rev. Anal. Chem., 41, 282 (2011)
  79. Gupta VK, Atar N, Yola ML, Ustundag Z, Uzun L, Water Res., 48, 210 (2014)
  80. Ahmaruzzaman M, Gupta VK, Ind. Eng. Chem. Res., 50(24), 13589 (2011)
  81. Asfaram A, Ghaedi M, Agarwal S, Tyagi I, Gupta VK, RSC Adv., 5, 18438 (2015)