화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.6, 1303-1311, June, 2018
DOI10.1007/s11814-018-0033-9  Export Citation
Adsorption of Congo Red dye by native amine and carboxyl modified biomass of Funalia trogii: Isotherms, kinetics and thermodynamics mechanisms
Gulay Bayramoglu1, 2, †, and Mehmet Yakup Arica3
  • 1Biochemical Processing and Biomaterial Research Laboratory, Gazi University, 06500 Ankara, Turkey
  • 2Department of Chemistry, Faculty of Sciences, Gazi University, 06500 Ankara, Turkey
  • 3Biochemical Processing and Biomaterial Research Laboratory, Gazi University, 06500 Ankara, Turkey, Korea
E-mail:
Native, iminodiacetic acid and triethylenetetraamine modified biomasses of Funalia trogii were used for removal of Congo Red dye (CRD) from aqueous medium. The native and modified fungal biomasses were characterized using ATR-FTIR, Zeta potential, contact angle studies and analytical methods. FTIR studies of the native and chemically modified adsorbent preparations show that amine, carboxyl and hydroxyl groups are involved in the adsorption of the model dye (i.e., Congo Red). The maximum adsorption of the CRD on the native, carboxyl and amine groups modified fungal biomasses was obtained at pH 5.0. The amount of adsorbed dye on the adsorbent samples increased as the initial concentration of CRD in the solution increased to 200mg/L. The adsorption capacities of native, carboxyl groups and amine modified fungal preparations were 90.4, 153.6 and 193.7mg/g dry adsorbents, respectively. The data was fitted well with the Langmuir isotherm model, and followed the pseudo-second-order equations. Thermodynamic parameters (ΔGo, ΔHo and ΔSo) were also calculated. The results showed that triethylenetetraamine (TETA) modified biomass of F. trogii presented an excellent dye removal performance and can be used in various environmental applications such as various micro-pollutants removal from aqueous medium.
Keywords:Fungal Biomass;Modification;Adsorption;Congo Red Dye;Surface Complexation;Wastewater Treatment
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