Conjugated polymer nano-ellipsoids assembled with octanoic acid and their polyurethane nanocomposites with simultaneous thermal storage and antibacterial activity

Dabin Lee; Tae Joo Shin; Pil J. Yoo; Kyung Wha Oh; Juhyun Park

Journal of Industrial and Engineering Chemistry, Vol.63, 33-40, July, 2018

DOI10.1016/j.jiec.2018.01.035 Export Citation

Conjugated polymer nano-ellipsoids assembled with octanoic acid and their polyurethane nanocomposites with simultaneous thermal storage and antibacterial activity

Dabin Lee, Tae Joo Shin¹, Pil J. Yoo^{2, †}, Kyung Wha Oh^{3, †}, and Juhyun Park^†

School of Chemical Engineering and Materials Science, Institute of Energy Converting Soft Materials, Chung-Ang University, Seoul 06974, Republic of Korea
¹UNIST Central Research Facilities & School of Natural Science, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea
²School of Chemical Engineering and SKKU Advanced Institute of Nanotechnology (SAINT), Suwon 16419, Republic of Korea
³Department of Fashion Design, Chung-Ang University, Seoul 06974, Republic of Korea

E-mail:, ,

We prepared conjugated polymer nano-ellipsoids (CPNs) via emulsification of chloroform phase using the octanoic acid (OA) in dimethyl formamide (DMF), followed by the removal of chloroform by heating. The resulting CPN DMF solutions were thoroughly mixed with polyurethane (PU) DMF solutions to form composite films upon solvent removal, with uniformly distributed CPNs due to hydrogen bonds between PU matrix and the CPNs. Superior photothermal and antibacterial properties of the PU:CPN composite films were observed, presenting the usefulness of CPNs as an efficient light harvester and thermal storage material, and the OA as an antibacterial material for multifunctional fiber applications.

Keywords:Conjugated polymers;Nano-ellipsoids;Polyurethanes;Antibacterial;Thermal storage

[References]

Wickramasinghe SR, Semmens MJ, Cussler EL, J. Membr. Sci., 84, 1 (1993)
Yoon JW, Park Y, Kim J, Park CH, Fash. Text., 4, 9 (2017)
Huang Y, Hu H, Huang Y, Zhu M, Meng W, Liu C, et al., ACS Nano, 9, 4766 (2015)
Nam YS, Cui XM, Jeong L, Lee JY, Park WH, Thin Solid Films, 517(24), 6531 (2009)
Schwarzkoff P, Kieffer R, Refractory Hard Metals: Borides, Carbides, Nitrides and Silicides, The Macmillan Company, New York, 1953.
He XM, Shu L, Li HB, Weng D, J. Mater. Res., 14, 615 (1999)
Reynolds GH, Janvier JC, Kaae JL, Morlevat JP, J. Nucl. Mater., 62, 9 (1976)
Cockeram BV, Measures DP, Mueller AJ, Thin Solid Films, 355-356, 17 (1999)
Mondal S, Appl. Therm. Eng., 28, 1536 (2008)
Lemire JA, Harrison JJ, Turner RJ, Nat. Rev. Microbiol., 11, 371 (2013)
Dhiman G, Chakraborty JN, Fash. Text., 2, 13 (2015)
Yoon J, Kwag J, Shin TJ, Park J, Lee YM, Lee Y, Park J, Heo J, Joo C, Park TJ, Yoo PJ, Kim S, Park J, Adv. Mater., 26(26), 4559 (2014)
Geng J, Sun C, Liu J, Liao LD, Yuan Y, Thakor N, Wang J, Liu B, Small, 11, 1603 (2014)
Kim CH, Kim SY, Lim YT, Lee TS, Macromol. Res., 25(6), 572 (2017)
Pu KY, Shuhendler AJ, Jokerst JV, Mei JG, Gambhir SS, Bao ZN, Rao JH, Nat. Nanotechnol., 9(3), 233 (2014)
Cui L, Rao J, WIREs, Nanomed. Nanobiotechnol., 9, e1418 (2017)
Park JH, J. Ind. Eng. Chem., 51, 27 (2017)
Liras M, Iglesias M, Sanchez F, Macromolecules, 49(5), 1666 (2016)
Carballeira NM, Prog. Lipid Res., 47, 50 (2008)
McDonough V, Stukey J, Cavanagh T, Biochim. Biophys. Acta, 2002, 109 (1581)
Rodriquez-Moya M, Gonzalez R, J. Proteom., 122, 86 (2015)
Huang CB, Alimova Y, Myers TM, Ebersole JL, Arch. Oral Biol., 56, 650 (2011)
Guo YJ, Pan ZZ, Chen CQ, Hu YH, Liu FJ, Shi Y, Yan JH, Chen QX, Appl. Biochem. Biotechnol., 162(6), 1564 (2010)
Peet J, Kim JY, Coates NE, Ma WL, Moses D, Heeger AJ, Bazan GC, Nat. Mater., 6(7), 497 (2007)
Lee KS, El-Sayed MA, J. Phys. Chem. B, 110(39), 19220 (2006)
Rai M, Yadav A, Gade A, Biotechnol. Adv., 27, 76 (2009)
Pastoriza-Santos I, Liz-Marzan LM, Langmuir, 15(4), 948 (1999)
Choi YK, Lee D, Lee SY, Shin TJ, Park J, Ahn DJ, Macromolecules, 50(17), 6935 (2017)
Bae N, Park HE, Yoo PJ, Shin TJ, Park JH, J. Ind. Eng. Chem., 51, 172 (2017)
Zang L, Che Y, Moore JS, Accounts Chem. Res., 41, 1596 (2008)
Seo D, Park J, Shin TJ, Yoo PJ, Park J, Kwak K, Macromol. Res., 23(6), 574 (2015)
Mutsuhisa F, Ken K, Shohei N, Polymer, 487, 997 (2007)
Clemitson I, Castalble Polyurethane Elastomers, Taylor & Francis Group, New York, 2008.
Kim JS, Kuk E, Yu KN, Kim JH, Park SJ, Lee HJ, et al., Nanomedicine, 3, 95 (2007)
Kim TS, Cha JR, Gong MS, Macromol. Res., 25(8), 856 (2017)
Madhav H, Singh P, Singh N, Jaiswar G, Macromol. Res., 25(7), 689 (2017)
Shivananda CS, Asha S, Madhukumar R, Satish S, Narayana B, Byrappa K, Wang Y, Sangappa Y, Macromol. Res., 24(8), 684 (2016)

[Referenced By]

[1] Wickramasinghe SR, Semmens MJ, Cussler EL, J. Membr. Sci., 84, 1 (1993)

[2] Yoon JW, Park Y, Kim J, Park CH, Fash. Text., 4, 9 (2017)

[3] Huang Y, Hu H, Huang Y, Zhu M, Meng W, Liu C, et al., ACS Nano, 9, 4766 (2015)

[4] Nam YS, Cui XM, Jeong L, Lee JY, Park WH, Thin Solid Films, 517(24), 6531 (2009)

[5] Schwarzkoff P, Kieffer R, Refractory Hard Metals: Borides, Carbides, Nitrides and Silicides, The Macmillan Company, New York, 1953.

[6] He XM, Shu L, Li HB, Weng D, J. Mater. Res., 14, 615 (1999)

[7] Reynolds GH, Janvier JC, Kaae JL, Morlevat JP, J. Nucl. Mater., 62, 9 (1976)

[8] Cockeram BV, Measures DP, Mueller AJ, Thin Solid Films, 355-356, 17 (1999)

[9] Mondal S, Appl. Therm. Eng., 28, 1536 (2008)

[10] Lemire JA, Harrison JJ, Turner RJ, Nat. Rev. Microbiol., 11, 371 (2013)

[11] Dhiman G, Chakraborty JN, Fash. Text., 2, 13 (2015)

[12] Yoon J, Kwag J, Shin TJ, Park J, Lee YM, Lee Y, Park J, Heo J, Joo C, Park TJ, Yoo PJ, Kim S, Park J, Adv. Mater., 26(26), 4559 (2014)

[13] Geng J, Sun C, Liu J, Liao LD, Yuan Y, Thakor N, Wang J, Liu B, Small, 11, 1603 (2014)

[14] Kim CH, Kim SY, Lim YT, Lee TS, Macromol. Res., 25(6), 572 (2017)

[15] Pu KY, Shuhendler AJ, Jokerst JV, Mei JG, Gambhir SS, Bao ZN, Rao JH, Nat. Nanotechnol., 9(3), 233 (2014)

[16] Cui L, Rao J, WIREs, Nanomed. Nanobiotechnol., 9, e1418 (2017)

[17] Park JH, J. Ind. Eng. Chem., 51, 27 (2017)

[18] Liras M, Iglesias M, Sanchez F, Macromolecules, 49(5), 1666 (2016)

[19] Carballeira NM, Prog. Lipid Res., 47, 50 (2008)

[20] McDonough V, Stukey J, Cavanagh T, Biochim. Biophys. Acta, 2002, 109 (1581)

[21] Rodriquez-Moya M, Gonzalez R, J. Proteom., 122, 86 (2015)

[22] Huang CB, Alimova Y, Myers TM, Ebersole JL, Arch. Oral Biol., 56, 650 (2011)

[23] Guo YJ, Pan ZZ, Chen CQ, Hu YH, Liu FJ, Shi Y, Yan JH, Chen QX, Appl. Biochem. Biotechnol., 162(6), 1564 (2010)

[24] Peet J, Kim JY, Coates NE, Ma WL, Moses D, Heeger AJ, Bazan GC, Nat. Mater., 6(7), 497 (2007)

[25] Lee KS, El-Sayed MA, J. Phys. Chem. B, 110(39), 19220 (2006)

[26] Rai M, Yadav A, Gade A, Biotechnol. Adv., 27, 76 (2009)

[27] Pastoriza-Santos I, Liz-Marzan LM, Langmuir, 15(4), 948 (1999)

[28] Choi YK, Lee D, Lee SY, Shin TJ, Park J, Ahn DJ, Macromolecules, 50(17), 6935 (2017)

[29] Bae N, Park HE, Yoo PJ, Shin TJ, Park JH, J. Ind. Eng. Chem., 51, 172 (2017)

[30] Zang L, Che Y, Moore JS, Accounts Chem. Res., 41, 1596 (2008)

[31] Seo D, Park J, Shin TJ, Yoo PJ, Park J, Kwak K, Macromol. Res., 23(6), 574 (2015)

[32] Mutsuhisa F, Ken K, Shohei N, Polymer, 487, 997 (2007)

[33] Clemitson I, Castalble Polyurethane Elastomers, Taylor & Francis Group, New York, 2008.

[34] Kim JS, Kuk E, Yu KN, Kim JH, Park SJ, Lee HJ, et al., Nanomedicine, 3, 95 (2007)

[35] Kim TS, Cha JR, Gong MS, Macromol. Res., 25(8), 856 (2017)

[36] Madhav H, Singh P, Singh N, Jaiswar G, Macromol. Res., 25(7), 689 (2017)

[37] Shivananda CS, Asha S, Madhukumar R, Satish S, Narayana B, Byrappa K, Wang Y, Sangappa Y, Macromol. Res., 24(8), 684 (2016)