Porous PEDOT.SiO2 hybrid conductive micro particles prepared by simultaneous co-vaporized vapor phase polymerization

Seul Gi Jung; Kuk Young Cho; Jin-Heong Yim

Journal of Industrial and Engineering Chemistry, Vol.63, 95-102, July, 2018

DOI10.1016/j.jiec.2018.02.003 Export Citation

Porous PEDOT.SiO2 hybrid conductive micro particles prepared by simultaneous co-vaporized vapor phase polymerization

Seul Gi Jung, Kuk Young Cho^{1, †}, and Jin-Heong Yim^†

Division of Advanced Materials Engineering, Kongju National University, Budaedong 275, Seobuk-gu, Cheonan-si, Chungnam 31080, South Korea
¹Department of Materials Science and Chemical Engineering, Hanyang University, 55 Hanyangdaehak-ro, Sangnok-gu, Ansan, South Korea

E-mail:,

Porous PEDOT-SiO2 particles were successfully prepared using simultaneous co-vaporized vapor phase polymerization (SC-VPP). By controlling the TEOS content, the morphologies of the obtained particles could be tuned from appearance of hollow egg shells aggregates to the hybrid particle composed of microspheres. Despite only having up to 40% of TEOS in the SC-VPP process, SiO2 accounts for over 90% of the resulting hybrid particle, because the hydrolysis/condensation reactions of TEOS would be much faster as compared with the PEDOT polymerization. The specific capacitance of a single hybrid particle decreased with increasing SiO2 portion, owing to changes in its external/internal structures.

Keywords:Polymer.matrix composites (PMCs);Electrical properties;Porosity;Electron microscopy;Simultaneous co-vaporized vapor phase;polymerization

[References]

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[2] Irimia-Vladu M, Chem. Soc. Rev., 43, 588 (2014)

[3] Gerard M, Chaubey A, Malhotra BD, Biosens. Bioelectron., 17, 345 (2002)

[4] Guimard NK, Gomez N, Schmidt CE, Prog. Polym. Sci, 32, 876 (2007)

[5] Levermore PA, Chen L, Wang X, Das R, Bradley DDC, Adv. Mater., 19, 2385 (2007)

[6] Welsh DM, Kumar A, Meijer EW, Reynolds JR, Adv. Mater., 16, 1379 (1999)

[7] Lee KS, Yun JH, Han YH, Yim JH, Park NG, Cho KY, Park JH, J. Mater. Chem., 21, 15193 (2011)

[8] D’Arcy JM, El-Kady MF, Khine PP, Zhang L, Lee SH, Davis NR, et al., ACS Nano, 8, 1500 (2014)

[9] Ahn J, Yoon S, Jung SG, Yim JH, Cho KY, J. Mater. Chem. A, 5, 21214 (2017)

[10] Nardes AM, Kemerink M, Kok MMD, Vinken E, Maturova K, Janssen RAJ, Org. Electron., 9, 727 (2008)

[11] Somboonsub B, Invernale MA, Thongyai S, Praserthdam P, Scola DA, Sotzing GA, Polymer, 51(6), 1231 (2010)

[12] Wei Y, Yeh JM, Jin D, Jia X, Wang J, Jang GW, Chen C, Gumbs RW, Chem. Mater., 7, 969 (1995)

[13] Zeng X, Zhou T, Leng C, Zang Z, Wang M, Hu W, Tang X, Lu S, Fang L, Zhou M, J. Mater. Chem. A., 5, 1749 (2017)

[14] Pang I, Kim S, Lee J, J. Nanosci. Nanotechnol., 7, 3792 (2007)

[15] Vosgueritchian M, Lipomi DJ, Bao ZA, Adv. Funct. Mater., 22(2), 421 (2012)

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[17] Song D, Li M, Li Y, Zhao X, Jiang B, Jiang Y, ACS Appl. Mater Interfaces, 6, 7126 (2014)

[18] Liu E, Liu C, Zhu Z, Xu J, Jiang F, Wang T, Li C, J. Comp. Mater., 1 (2017)

[19] Richards JJ, Scherbarth AD, Wagner NJ, Butler PD, ACS Appl. Mater Interfaces, 8, 24089 (2016)

[20] Hatzell KB, Boota M, Gogotsi Y, Chem. Soc. Rev., 44, 8664 (2015)

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[22] Yim JH, Compos. Sci. Techol., 86, 45 (2013)

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[25] Kim SW, Lee SW, Kim J, Yim JH, Cho KY, Polymer, 102, 127 (2016)

[26] Choi JS, Park JS, Kim B, Lee BT, Yim JH, Polymer, 120, 95 (2017)

[27] Adeloju SB, Wallace GG, Analyst, 121, 699 (1996)

[28] Chung BG, Lee KH, Khademhosseini A, Lee SH, Lab Chip, 12, 45 (2012)

[29] Mumtaz M, de Cuendias A, Putaux JL, Cloutet E, Cramail H, Macromol. Rapid Commun., 27(17), 1446 (2006)

[30] Choi JW, Han MG, Kim SY, Oh SG, Im SS, Synth. Met., 141, 293 (2004)

[31] Han MG, Foulger SH, ChemComm, 20, 2054 (2004)

[32] Park MK, Onishi K, Locklin J, Caruso F, Advincula RC, Langmuir, 19(20), 8550 (2003)

[33] Xu S, Nie Z, Seo M, Lewis P, Kumacheva E, Stone HA, Garstecki P, Weibel DB, Gitlin I, Whitesides GM, Angew. Chem., 117, 734 (2005)

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[36] Gong XQ, Wen WJ, Sheng P, Langmuir, 25(12), 7072 (2009)

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[38] Hwangbo KH, Kim MR, Lee CS, Cho KY, Soft Matter, 7, 10874 (2011)