Sensitive and selective heavy metal ion, Mn2+ sensor development based on the synthesized (E)-N0-chlorobenzylidene-benzenesulfonohydrazide (CBBSH) molecules modified with nafion matrix

Abdullah M. Asiri; Mohammad M. Hussain; Muhammad N. Arshad; Mohammed M. Rahman

Journal of Industrial and Engineering Chemistry, Vol.63, 312-321, July, 2018

DOI10.1016/j.jiec.2018.02.032 Export Citation

Sensitive and selective heavy metal ion, Mn2+ sensor development based on the synthesized (E)-N0-chlorobenzylidene-benzenesulfonohydrazide (CBBSH) molecules modified with nafion matrix

Abdullah M. Asiri^{1, 2, †}, Mohammad M. Hussain^{1, 2}, Muhammad N. Arshad^{1, 2}, and Mohammed M. Rahman^{1, 2, †}

¹Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
²Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

E-mail:,

A set of (E)-N'-chlorobenzylidene-benzenesulfonohydrazide (CBBSH) molecules were synthesized using a condensation method from the derivatives of chlorobenzaldehyde and benzenesulfonylhydrazine in a medium yield which crystallized in EtOH. CBBSH derivatives were characterized using highly refined spectroscopic techniques such as 1H NMR, 13C NMR, FT-IR, FESEM, and UV-Vis. Structure of the CBBSH compounds was confirmed using a single crystal X-ray diffraction technique (SCXRDT) and applied for the potential detection of selective heavy metal ion (HMI), manganese ion (Mn2+) by using reliable electrochemical method. A small layer of CBBSH was deposited onto a smooth GCE with coating binder in order to modify a sensitive and selective Mn2+ sensor. Analytical parameters such as sensitivity, LOD, LOQ of the modified sensor (3-CBBSH/GCE) toward Mn2+ were calculated from the calibration curve (CC) as 1270.0 pA μM-1cm-2, ≈10.0 pM, and 335.0 mM respectively. This prospective 3-CBBSH/GCE sensor used to the selective measurement of Mn2+ in spiked real samples for example industrial effluent and various water samples (red sea, surface, and tap), and found acceptable and rational results.

Keywords:(E)-N'-Chlorobenzylidene-benzenesulfonohydrazide;Condensation method;Heavy metal ions;Glassy carbon electrode;Health care safety

[References]

Du X, Liu GY, Qu FS, Li K, Shao SL, Li GB, Liang H, Desalination, 403, 97 (2017)
Freitas PS, Clarke LJ, Kennedy H, Richardson CA, Geochim. Cosmochim. Acta, 194, 266 (2016)
Vries D, Bertelkamp C, Kegel FS, Hofs B, Dusseldorp J, Bruins JH, Vet WD, Akker BVD, Water Res., 109, 35 (2017)
Li Q, He Y, Sens. Actuators B-Chem., 243, 454 (2017)
Rahman MM, Hussain MM, Asiri AM, Prog. Nat. Sci.: Mater. Int., 27, 566 (2017)
Hussain MM, Rahman MM, Asiri AM, J. Environ. Sci., 53, 27 (2017)
Rahman MM, Hussain MM, Asiri AM, New J. Chem., 41, 6667 (2017)
Rahman MM, Hussain MM, Asiri AM, PLOS ONE, 12, e01778 (2017)
Rahman MM, Hussain MM, Asiri AM, PLOS ONE, 11, e10662 (2016)
Rahman MM, Hussain MM, Asiri AM, Microchim. Acta, 183, 3255 (2016)
Rahman MM, Hussain MM, Asiri AM, Microchim. Acta, 183, 3265 (2016)
Hussain MM, Rahman MM, Asirim AM, Awual MR, RSC Adv., 6, 80511 (2016)
Rahman MM, Hussain MM, Asiri AM, RSC Adv., 6, 65338 (2016)
Shu JC, Liu RL, Liu ZH, Chen HL, Tao CY, J. Electroanal. Chem., 780, 32 (2016)
Qiao C, Sun L, Zhang S, Wei Q, Zhou C, Xie G, Chen S, Yang X, Gao S, Polyhedron, 119, 445 (2016)
Agilent, Crys. Alis PRO, Agilent Technologies, England, 2012.
Sheldrick GM, Acta Crystallogr. Sect. A, 64, 112 (2008)
Spek AL, Crystal & Structural Chemistry, Utrecht University, Utrecht, 2005.
Farrugia LJ, J. Appl. Cryst., 32, 837 (1999)
Farrugia LJ, J. Appl. Cryst., 45, 849 (2012)
Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H, J. Appl. Crystallogr., 42, 339 (2009)
Hussain MM, Rahman MM, Arshad MN, Asiri AM, ACS Omega, 2, 420 (2017)
Arshad MN, Sahin O, Zia-ur-Rahman M, Khan IU, Asiri AM, Rafique HM, J. Struct. Chem., 54, 437 (2013)
Arshad MN, Sahin O, Zia-ur-Rehman M, Shafiq M, Khan IU, Asiri AM, Khan SB, Alamry KA, J. Chem. Cryst., 43, 671 (2013)
Arshad MN, Mahmood T, Khan AF, Zia-Ur-Rehman M, Asiri AM, Khan IU, Un-Nisa R, Ayub K, Mukhtar A, Saeed MT, Chin. J. Struct. Chem., 34, 15 (2015)
Shafiq M, Khan IU, Zia-Ur-Rehman M, Asghar MN, Asiri AM, Arshad MN, Asian J. Chem., 24, 4799 (2012)
Bernstein J, Davis RE, Shimoni L, Chang NL, Angew. Chem.-Int. Edit., 34, 1555 (1995)
Hussain MM, Rahman MM, Arshad MN, Asiri AM, Sci. Rep., 7, 5832 (2017)
Hussain MM, Rahman MM, Arshad MN, Asiri AM, Chem. Select, 2, 7455 (2017)
Hussain MM, Asiri AM, Arshad MN, Rahman MM, New J. Chem., 42, 1169 (2018)
Badocco D, Pastore P, Favaro G, Macca C, Talanta, 72, 249 (2007)
Li B, Zhang Z, Liu W, Anal. Sci., 17, 1347 (2001)
Zhou YX, Zhu GY, Talanta, 44, 2041 (1997)
He Y, Zhang XH, Sens. Actuators B-Chem., 222, 320 (2016)
Narayanan KB, Park HH, Spectrochim. Acta A, 131, 132 (2014)
Annadhasan M, Muthukumarasamyvel T, Babu VRS, Najendiran N, ACS Sustain. Chem. Eng., 2, 887 (2014)
Gao YX, Xin JW, Shen ZY, Pan W, Li X, Wu AG, Sens. Actuators B-Chem., 181, 288 (2013)
Hu R, Zhang L, Li HB, New J. Chem., 38, 2237 (2014)
Mao XW, Su HY, Tian DM, Li HB, Yang RH, ACS Appl. Mater. Interfaces, 5, 592 (2013)
Arain MS, Kazi TG, Afridi HI, Arain SA, Ali J, Arain SS, Shanker B, J. Anal. At. Spectrom., 29, 2349 (2014)
Tokman N, Akman S, Ozeroglu C, Talanta, 63, 699 (2004)
Coffey MJ, Jickells TD, Coast. Shelf Sci., 40, 379 (1995)
Amais RS, Donati GL, Nobrega JA, Anal. Chim. Acta, 706, 223 (2011)

[Referenced By]

[1] Du X, Liu GY, Qu FS, Li K, Shao SL, Li GB, Liang H, Desalination, 403, 97 (2017)

[2] Freitas PS, Clarke LJ, Kennedy H, Richardson CA, Geochim. Cosmochim. Acta, 194, 266 (2016)

[3] Vries D, Bertelkamp C, Kegel FS, Hofs B, Dusseldorp J, Bruins JH, Vet WD, Akker BVD, Water Res., 109, 35 (2017)

[4] Li Q, He Y, Sens. Actuators B-Chem., 243, 454 (2017)

[5] Rahman MM, Hussain MM, Asiri AM, Prog. Nat. Sci.: Mater. Int., 27, 566 (2017)

[6] Hussain MM, Rahman MM, Asiri AM, J. Environ. Sci., 53, 27 (2017)

[7] Rahman MM, Hussain MM, Asiri AM, New J. Chem., 41, 6667 (2017)

[8] Rahman MM, Hussain MM, Asiri AM, PLOS ONE, 12, e01778 (2017)

[9] Rahman MM, Hussain MM, Asiri AM, PLOS ONE, 11, e10662 (2016)

[10] Rahman MM, Hussain MM, Asiri AM, Microchim. Acta, 183, 3255 (2016)

[11] Rahman MM, Hussain MM, Asiri AM, Microchim. Acta, 183, 3265 (2016)

[12] Hussain MM, Rahman MM, Asirim AM, Awual MR, RSC Adv., 6, 80511 (2016)

[13] Rahman MM, Hussain MM, Asiri AM, RSC Adv., 6, 65338 (2016)

[14] Shu JC, Liu RL, Liu ZH, Chen HL, Tao CY, J. Electroanal. Chem., 780, 32 (2016)

[15] Qiao C, Sun L, Zhang S, Wei Q, Zhou C, Xie G, Chen S, Yang X, Gao S, Polyhedron, 119, 445 (2016)

[16] Agilent, Crys. Alis PRO, Agilent Technologies, England, 2012.

[17] Sheldrick GM, Acta Crystallogr. Sect. A, 64, 112 (2008)

[18] Spek AL, Crystal & Structural Chemistry, Utrecht University, Utrecht, 2005.

[19] Farrugia LJ, J. Appl. Cryst., 32, 837 (1999)

[20] Farrugia LJ, J. Appl. Cryst., 45, 849 (2012)

[21] Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H, J. Appl. Crystallogr., 42, 339 (2009)

[22] Hussain MM, Rahman MM, Arshad MN, Asiri AM, ACS Omega, 2, 420 (2017)

[23] Arshad MN, Sahin O, Zia-ur-Rahman M, Khan IU, Asiri AM, Rafique HM, J. Struct. Chem., 54, 437 (2013)

[24] Arshad MN, Sahin O, Zia-ur-Rehman M, Shafiq M, Khan IU, Asiri AM, Khan SB, Alamry KA, J. Chem. Cryst., 43, 671 (2013)

[25] Arshad MN, Mahmood T, Khan AF, Zia-Ur-Rehman M, Asiri AM, Khan IU, Un-Nisa R, Ayub K, Mukhtar A, Saeed MT, Chin. J. Struct. Chem., 34, 15 (2015)

[26] Shafiq M, Khan IU, Zia-Ur-Rehman M, Asghar MN, Asiri AM, Arshad MN, Asian J. Chem., 24, 4799 (2012)

[27] Bernstein J, Davis RE, Shimoni L, Chang NL, Angew. Chem.-Int. Edit., 34, 1555 (1995)

[28] Hussain MM, Rahman MM, Arshad MN, Asiri AM, Sci. Rep., 7, 5832 (2017)

[29] Hussain MM, Rahman MM, Arshad MN, Asiri AM, Chem. Select, 2, 7455 (2017)

[30] Hussain MM, Asiri AM, Arshad MN, Rahman MM, New J. Chem., 42, 1169 (2018)

[31] Badocco D, Pastore P, Favaro G, Macca C, Talanta, 72, 249 (2007)

[32] Li B, Zhang Z, Liu W, Anal. Sci., 17, 1347 (2001)

[33] Zhou YX, Zhu GY, Talanta, 44, 2041 (1997)

[34] He Y, Zhang XH, Sens. Actuators B-Chem., 222, 320 (2016)

[35] Narayanan KB, Park HH, Spectrochim. Acta A, 131, 132 (2014)

[36] Annadhasan M, Muthukumarasamyvel T, Babu VRS, Najendiran N, ACS Sustain. Chem. Eng., 2, 887 (2014)

[37] Gao YX, Xin JW, Shen ZY, Pan W, Li X, Wu AG, Sens. Actuators B-Chem., 181, 288 (2013)

[38] Hu R, Zhang L, Li HB, New J. Chem., 38, 2237 (2014)

[39] Mao XW, Su HY, Tian DM, Li HB, Yang RH, ACS Appl. Mater. Interfaces, 5, 592 (2013)

[40] Arain MS, Kazi TG, Afridi HI, Arain SA, Ali J, Arain SS, Shanker B, J. Anal. At. Spectrom., 29, 2349 (2014)

[41] Tokman N, Akman S, Ozeroglu C, Talanta, 63, 699 (2004)

[42] Coffey MJ, Jickells TD, Coast. Shelf Sci., 40, 379 (1995)

[43] Amais RS, Donati GL, Nobrega JA, Anal. Chim. Acta, 706, 223 (2011)