화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.64, 311-317, August, 2018
DOI10.1016/j.jiec.2018.03.029  Export Citation
Enhancement of surface stability of lithium manganese oxide spinel by silyl-group functionalized fluoride-responsive ionic liquid additives
Hyoree Seo, Subin Na, Boeun Lee, Taeeun Yim1, †, and Si Hyoung Oh†
  • Korea Institute of Science and Technology, Seongbuk-gu, Seoul 02792, Republic of Korea
  • 1Department of Chemistry, Incheon National University, Incheon 22012, Republic of Korea
E-mail:,
Spinel-structured lithium manganese oxides are considered as promising cathode material, however, their widespread commercial application remains hampered by their poor surface instability. To overcome these problems, we designed and synthesized task-specific ionic liquid additives that can effectively scavenge trace amounts of fluoride in the cell. Addition of ionic liquid additives in the electrolyte significantly improves cycling retention. 1H- and 19F-nuclear magnetic resonance spectroscopy measurements and inductively coupled plasma mass spectrometry elemental analysis collaboratively provides clear evidence that the ionic liquid additives selectively suppress parasitic reactions of the electrolyte with the surface of lithium manganese oxides cathode.
Keywords:Surface stability;Cathode;Lithium manganese oxides;Silyl functional group;Electrolyte additive
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