화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.64, 467-477, August, 2018
DOI10.1016/j.jiec.2018.04.008  Export Citation
Fluidizable Ni/Ce-meso-Al2O3 for gasification of glucose: Effect of catalyst reduction on hydrogen selectivity
Sagir Adamu, Shaikh A. Razzak, and Mohammad M. Hossain†
  • Department of Chemical Engineering and KACST TIC for CCS, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia
E-mail:
A new template-free technique is applied to develop fluidizable Ce-Al2O3 support and impregnated with nickel. The Ni(x)/Ce-Al2O3 catalysts are evaluated in a fluidized CREC Riser Simulator using glucose as biomass surrogate. XRD shows that nickel is well-dispersed on Ce-Al2O3. The acidity of the catalysts decreased from 0.317 to 0.202 mmol NH3/g-sample as the nickel loading was increased. In catalyst evaluation, it is found that the reduced catalysts favor bond cleavage, promotes water gas shift and steam reforming reactions to give hydrogen/syngas as more selective products. Ni(20)/Ce-Al2O3 exhibited lowest extent of coking and produced hydrogen rich syngas with H2/CO ≈ 1.75:1.
Keywords:Ceria-doped alumina;Thermal stability;Catalyst regeneration;Catalyst recyclability;Hydrogen selectivity;Syngas composition
  1. Richardson Y, Blin J, Julbe A, Prog. Energy Combust. Sci., 38(6), 765 (2012)
  2. Birol F, Cozzi L, Gould T, Bromhead A, Priddle R, World Energy Outlook, 2015, 1 (2015)
  3. Seddiek IS, Elgohary MM, Int. J. Nav. Archit. Ocean Eng., 6(3), 737 (2014)
  4. Dignon J, Atmos. Environ. A: Gen. Top., 26(6), 1157 (1992)
  5. Yakaboylu O, Harinck J, Smit K, de Jong W, Energies, 8(2), 859 (2015)
  6. Bona S, Guillen P, Alcalde JG, Garcia L, Bilbao R, Chem. Eng. J., 137(3), 587 (2008)
  7. Nguyen TS, He SB, Raman G, Seshan K, Chem. Eng. J., 299, 415 (2016)
  8. Nguyen HT, Yoda E, Komiyama M, Chem. Eng. Sci., 109, 197 (2014)
  9. Bridgwater AV, Chem. Eng. J., 91(2-3), 87 (2003)
  10. Castello D, Kruse A, Fiori L, Chem. Eng. J., 228, 535 (2013)
  11. Chowdhury MBI, Hossain MM, Charpentier PA, Appl. Catal. A: Gen., 405(1-2), 84 (2011)
  12. Mazumder J, de Lasa H, Appl. Catal. B: Environ., 160, 67 (2014)
  13. de Lasa H, Salaices E, Mazumder J, Lucky R, Chem. Rev., 111(9), 5404 (2011)
  14. Basu P, Mettanant V, Int. J. Chem. React. Eng., 7 (2009)
  15. Kruse A, Dahmen N, J. Supercrit. Fluids, 96, 36 (2015)
  16. Manzour PA, Hydrogen Production Using Catalytic Supercritical Water Gasification of Lignocellulosic Biomass, (2012).
  17. Byrd AJ, Pant KK, Gupta RB, Fuel, 87(13-14), 2956 (2008)
  18. Yang RX, Chuang KH, Wey MY, Energy Fuels, 29(12), 8178 (2015)
  19. Wu C, Williams PT, Environ. Sci. Technol., 7, 5993 (2010)
  20. Cengiz NU, Yildiz G, Sert M, Gokkaya DS, Saglam M, Yuksel M, Ballice L, Int. J. Hydrog. Energy, 40(43), 14806 (2015)
  21. Deshmane VG, Owen SL, Abrokwah RY, Kuila D, J. Mol. Catal. A-Chem., 408, 202 (2015)
  22. de Andres JM, Narros A, Rodriguez ME, Fuel, 90(2), 521 (2011)
  23. Zhang LH, Champagne P, Xu CB, Int. J. Hydrog. Energy, 36(16), 9591 (2011)
  24. Azadi P, Afif E, Azadi F, Farnood R, Green Chem., 14(6), 1766 (2012)
  25. Chan FL, Tanksale A, Renew. Sust. Energ. Rev., 38, 428 (2014)
  26. Miranda BC, Chimentao RJ, Santos JBO, Gispert-Guirado F, Llorca J, Medina F, Bonillo FL, Sueiras JE, Appl. Catal. B: Environ., 147, 464 (2014)
  27. Ashik UPM, Daud WMAW, RSC Adv., 5, 67227 (2015)
  28. Choi SO, Ahn IY, Moon SH, Korean J. Chem. Eng., 26(5), 1252 (2009)
  29. Sanchez-Sanchez MC, Navarro RM, Fierro JLG, Int. J. Hydrog. Energy, 32(10-11), 1462 (2007)
  30. Zeng Y, Ma HF, Zhang HT, Ying WY, Fang DY, Fuel, 162, 16 (2015)
  31. Piras A, Colussi S, Trovarelli A, Sergo V, Llorca J, Psaro R, Sordelli L, J. Phys. Chem. B, 109(22), 11110 (2005)
  32. Luisetto I, Tuti S, Battocchio C, Lo Mastro S, Sodo A, Appl. Catal. A: Gen., 500, 12 (2015)
  33. Koo KY, Roh HS, Jung UH, Yoon WL, Catal. Lett., 130(1-2), 217 (2009)
  34. Tomer A, Yan Z, Ponchel A, Pera-Titus M, J. Catal., 356, 133 (2017)
  35. Quddus MR, Hossain MM, de Lasa HI, Catal. Today, 210, 124 (2013)
  36. Li DL, Tamura M, Nakagawa Y, Tomishige K, Bioresour. Technol., 178, 53 (2015)
  37. Khelfa A, Bensakhria A, Weber JV, J. Anal Appl. Pyrolysis, 101, 111 (2013)
  38. Richardson Y, Motuzas J, Julbe A, Volle G, Blin J, J. Phys. Chem. C, 45, 23812 (2013)
  39. Shen Y, Yoshikawa K, Ind. Eng. Chem., 53(27), 10929 (2014)
  40. Adamu S, Khan MY, Razzak SA, Hossain MM, J. Porous Mat., 24(5), 1343 (2017)
  41. Bortolozzi JP, Weiss T, Gutierrez LB, Ulla MA, Chem. Eng. J., 246, 343 (2014)
  42. Demsash HD, Mohan R, Int. J. Hydrog. Energy, 41(48), 22732 (2016)
  43. Charisiou ND, Siakavelas G, Papageridis KN, Baklavaridis A, Tzounis L, Avraam DG, Goula MA, J. Nat. Gas Sci. Eng., 31, 164 (2016)
  44. Barrett EP, Joyner LG, Halenda PP, J. Am. Chem. Soc., 73(1), 373 (1951)
  45. Hossain MM, Ind. Eng. Chem. Res., 56(15), 4309 (2017)
  46. Hossain MM, Lopez D, Herrera J, de Lasa HI, Catal. Today, 143(1-2), 179 (2009)
  47. Huang F, Zheng Y, Li Z, Xiao Y, Zheng Y, Cai G, Wei K, Chem. Commun., 47(18), 5247 (2011)
  48. Tian J, Lu J, Brazilian J, Chem. Eng., 29(1), 121 (2012)
  49. Osorio-Vargas P, Flores-Gonzalez NA, Navarro RM, Fierro JLG, Campos CH, Reyes P, Catal. Today, 259 (2016)
  50. Richardson JT, Turk B, Twigg MV, Appl. Catal. A: Gen., 148(1), 97 (1996)
  51. Djebaili K, Mekhalif Z, Boumaza A, Djelloul A, J. Spectroscopy, 2015 (2015)
  52. Tao J, Zhao L, Dong C, Lu Q, Du X, Dahlquist E, Energies, 6(7), 3284 (2013)
  53. Cargnello M, Doan-Nguyen V, Gordon TR, Diaz RE, Stach EA, Gorte RJ, Fornasiero P, Murray CB, Science, 18, 124014 (2013)
  54. Kho ET, Jantarang S, Zheng Z, Scott J, Amal R, Engineering, 3(3), 393 (2017)
  55. Schmieder H, Abeln J, Boukis N, Dinjus E, Kruse A, Kluth M, Petrich G, Sadri E, Schacht M, J. Supercrit. Fluids, 17(2), 145 (2000)
  56. Lee IG, Kim MS, Ihm SK, Ind. Eng. Chem. Res., 41(5) (2002)
  57. Sinag A, Kruse A, Rathert J, Ind. Eng. Chem. Res., 43(2), 502 (2004)
  58. Byrd AJ, Pant KK, Gupta RB, Ind. Eng. Chem. Res., 46(11), 3574 (2007)
  59. Susanti RF, Dianningrum LW, Yum T, Kim Y, Lee BG, Kim J, Int. J. Hydrog. Energy, 37(16), 11677 (2012)
  60. Jin H, Lu Y, Guo L, Cao C, Zhang X, Int. J. Hydrog. Energy, 35(7), 3001 (2018)
  61. Susanti RF, Dianningrum LW, Yum T, Kim Y, Lee YW, Kim J, Chem. Eng. Res. Des., 92(10), 1834 (2014)
  62. Huang J, Lian X, Wang L, Zhu C, Jin H, Wang R, Int. J. Hydrogen Energy (2016) 1, doi:http://dx.doi.org/10.1016/j.ijhydene.2016.10.012.
  63. Adamu S, Binous H, Razzak SA, Hossain MM, Renew. Energy, 111, 399 (2017)
  64. Peymani M, Alavi SM, Rezaei M, Int. J. Hydrog. Energy, 41(42), 19057 (2016)
  65. Chuntanapum A, Matsumura Y, Ind. Eng. Chem., 49(9), 4055 (2010)
  66. Koo KY, Lee SH, Jung UH, Roh HS, Yoon WL, Fuel Process. Technol., 119, 151 (2014)
  67. Tsyganok AI, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T, J. Catal., 213(2), 191 (2003)
  68. Swierczynski D, Libs S, Courson C, Kiennemann A, Appl. Catal. B: Environ., 74(3-4), 211 (2007)
  69. Mazumder J, de Lasa HI, Chem. Eng. J., 293, 232 (2016)
  70. Argyle M, Bartholomew C, Catalysts, 5(1), 145 (2015)
  71. Zhu C, Guo LJ, Jin H, Huang JB, Li S, Lian XY, Int. J. Hydrog. Energy, 41(16), 6630 (2016)
  72. Lu YJ, Guo LJ, Zhang XM, Ji CM, Int. J. Hydrog. Energy, 37(4), 3177 (2012)
  73. Manukyan KV, Avetisyan A, Shuck C, Chatilyan H, Rouvimov S, Kharatyan S, Mukasyan AS, J. Phys. Chem. C, 119(218), 16131 (2015)