A high dielectric permittivity (epsilon') with a suppressed loss tangent (tan delta) can be obtained in poly(vinylidene fluoride) (PVDF) polymer nanocomposites using gold (Au)-deposited nano-BaTiO3 hybrid particles (Au-nBT) as fillers. Au-nBT hybrid particles were successfully prepared by a modified Turkevich method, while Au-nBT/PVDF nanocomposites were prepared using liquid-phase assisted dispersion and hot-pressing methods. Au nanoparticles with sizes of approximate to 10-30 nm were discretely grown on the nBT surface, which efficiently inhibited continuous contact between conductive Au nanoparticles and formation of conducting paths in the polymer matrix. This can cause suppression of conductivity and related tand values. Interestingly, epsilon' of the Au-nBT/PVDF nanocomposites increased from 26.7 to 158.2 (at 1 kHz) with increased filler loadings from 4 to 62 vol%, while tand slightly increased from 0.034 to 0.055 with very low conductivities (sigma < 10(-9) S/cm). Greatly enhanced epsilon' values that were slightly dependent on frequency in the range of 10(2) - 10(6) Hz are attributed to an enhanced local electric field strength, inducing stronger dipolar polarization in the Au-nBT/PVDF nanocomposites. (C) 2018 Elsevier B.V. All rights reserved.