Chemical Physics Letters, Vol.701, 98-102, 2018
Realizing performance improvement of blue thermally activated delayed fluorescence molecule DABNA by introducing substituents on the paraposition of boron atom
To seek effective thermally activated delayed fluorescence (TADF) molecules, we have designed compounds 1-4 by introducing substituents on the para-position of boron atom of blue TADF molecule (DABNA-1). The results indicate that 1-4 not only retain the blue emission from 454 to 466 nm, but also possess larger oscillator strength. Besides, the fluorescence radiative rates (k(r)) of 1-4 are higher than that of DABNA-1. The singlet-triplet energy splitting (Delta E-ST) values of designed compounds are smaller than that of DABNA-1. Taking both Delta E-ST and kr into account, designed compounds show better TADF performances, indicating their potential as TADF materials. (C) 2018 Elsevier B.V. All rights reserved.