화학공학소재연구정보센터
Chemistry Letters, Vol.47, No.5, 650-653, 2018
Mechanical Stimuli Induced Emission Spectra Blue Shift of Two D-A Type Phenothiazine Derivatives
Two D-A type phenothiazine derivatives were successfully designed and synthesized. Their typical solvatochromism was confirmed by spectroscopy. Experimental result also revealed that aggregation-induced emission (AIE) effect may be ascribed to the restriction of intramolecular rotation (RIR). Furthermore, both of them displayed blue-shifted mechanochromic behavior, which is clearly distinguished from their red-shifted precursor aldehyde. This kind of compound has a certain significance in the development and application of organic mechanochromic materials.