Ce0.6La0.4O2 (LDC) is a promising buffer layer for preventing chemical reactions between a doped-LaGaO3 electrolyte and Ni-based anode in intermediate-temperature solid oxide fuel cells (SOFCs). In the present work, first, the chemical compatibility between La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) powders and LDC powders is evaluated. Subsequently, an LDC buffer layer is prepared via atmospheric plasma spraying (APS) at different deposition temperatures using powders that have particle sizes larger than 30 mm. The effects of deposition temperature on the microstructure and ionic conductivity are investigated. Cells with an optimized APS LDC interlayer between the NiO containing anode and LSGM electrolyte are tested with humidified H-2 as fuel and ambient air as the oxidation. At 750 degrees C, the maximum power density of cells with the APS LDC interlayer is 460 mW/cm(2). In addition, a stability test of similar to 400 h at 650 degrees C under a constant current density of 250 mW/cm(2) is carried out, and the cell with the optimized APS LDC interlayer is stable. Therefore, APS is a viable alternative approach for fabricating an LDC interlayer for SOFCs using the LSGM electrolyte. (C) 2018 Elsevier Ltd. All rights reserved.