Journal of Polymer Science Part A: Polymer Chemistry, Vol.35, No.4, 735-740, 1997
Temperature-Dependence of Copolymerization Parameters in Ethene/1-Octene Copolymerization Using Homogeneous Rac-Me(2)Si(2-Mebenz (E)IND)(2)Zrcl2/Mao Catalyst
Ethene was copolymerized with 1-octene using homogeneous MAO-activated rac-Me(2)Si(2-MeBenz[e] Ind)(2)ZrCl2 at constant ethene concentration with temperature varying between 0 and 60 degrees C to determine a temperature dependence of copolymerization parameters. At constant 1-octene and ethene concentration (constant ethene/1-octene feed molar ratio) 1-octene incorporation decreased with increasing temperature. Furthermore, when ethene/1-octene molar ratio was varied by varying the temperature keeping 1-octene concentration and ethene pressure-constant, increasing temperature accounted for lower molecular masses without affecting 1-octene incorporation. An explanation for the observed temperature dependence of the copolymerization parameters is presented, considering the solution-enthalpy of the gaseous ethene in the solvent. In all cases amorphous poly(ethene-co-1-octene) with 1-octene content varying between 20 and 40 mol % was obtained.