The first structural and compositional details of a low-stage graphite interaction compound (GIC) containing Mg are reported, with the GIC obtained by combining magnesium metal and graphite powder in ethylenediamine (en) at 100 degrees C under an inert atmosphere. Thermal analyses indicate the bottle-green stage 1 product has a composition of [Mg(en)(1.0)]C-13. Xray diffraction shows a c-axis expansion of 0.55 nm, indicating the presence of intercalate monolayers with the en cointercalate oriented perpendicular to the encasing graphene layers. Redox titration indicates two electrons are transferred per Mg. A structural model is proposed with dimeric [Mg-2(en)(2)](2+) intercalate species.